Polymorphic crystallization of Cu2O compound

	Polymorphic crystallization of Cu2O compound
	Chen, Kunfeng ; Sun, Congting ; Song, Shuyan ; Xue,Dongfeng
刊名	crystengcomm
	2014
卷号	16 期号:24 页码:5257-5267
关键词	CUPROUS-OXIDE BRANCHING GROWTH CRYSTAL-GROWTH CO OXIDATION EVOLUTION SYSTEM ROUTE MNO2 SUPERCAPACITANCE MICROCRYSTALS
通讯作者	chen,kf
英文摘要	cu2o can crystallize into various polymorphs, such as cubes, rhombic dodecahedra, branching structures, and hopper cubes, instead of thermodynamically stable octahedra by designed kinetic-control routes instead of traditional thermodynamic control. the present results confirmed that cu2o polymorphs have distinct physical and chemical properties, and morphology changes can occur due to polymorphic transitions in a kinetics-controllable reaction system. both thermodynamic and kinetic factors on these polymorphism systems are believed to be significant for developing a polymorphism-property relationship, ultimately guiding the appropriate material selection for specific applications. furthermore, we took cu2o as an example to illustrate the development of "polymorphism" in modern materials science: polymorphism is an intrinsic physicochemical characteristic, and involves varying growth shapes, phase transformation and variation of physical properties. these findings can provide new insight to polymorphism-performance correlation and kinetic-thermodynamic control synthesis.
收录类别	SCI
语种	英语
WOS记录号	WOS:000336839900012
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/57230]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Chen, Kunfeng,Sun, Congting,Song, Shuyan,et al. Polymorphic crystallization of Cu2O compound[J]. crystengcomm,2014,16(24):5257-5267.
APA	Chen, Kunfeng,Sun, Congting,Song, Shuyan,&Xue,Dongfeng.(2014).Polymorphic crystallization of Cu2O compound.crystengcomm,16(24),5257-5267.
MLA	Chen, Kunfeng,et al."Polymorphic crystallization of Cu2O compound".crystengcomm 16.24(2014):5257-5267.