Simultaneous determination of dopamine, ascorbic acid and uric acid at electrochemically reduced graphene oxide modified electrode
Yang, La ; Liu, Dong ; Huang, Jianshe ; You,Tianyan
刊名sensors and actuators b-chemical
2014
卷号193期号:5页码:166-172
关键词GLASSY-CARBON ELECTRODE GRAPHITE OXIDE PYROLYTIC-GRAPHITE REDUCTION SENSITIVITY NANOFIBERS NANOTUBES OXIDATION DISEASE FILMS
通讯作者you,ty
英文摘要a facile electrochemical method was applied to prepare electrochemically reduced graphene oxide (ergo). the morphology and structure of ergo were characterized by scanning electron microscope (sem), x-ray photoelectron spectroscopy (xps), raman spectroscopy and x-ray diffraction (xrd). compared with the bare glassy carbon electrode (gce), ergo modified gce (ergo/gce) exhibits much higher electrocatalytic activities toward the oxidation of dopamine (da), ascorbic acid (aa) and uric acid (ua) with increasing of peak currents and decreasing of oxidation overpotentials. differential pulse voltammetry results show that da, aa and ua could be detected selectively and sensitively at ergo/gce with peak-to-peak separation of 240 mv and 130 mv for aa-da and da-ua, respectively. the linear ranges for aa, ua and da are 500-2000 mu m, 0.5-60 mu m and 0.5-60 mu m, respectively. meanwhile, due to the negligible response to physiological level of aa (0.1 mm), ergo/gce could be used for the determination of da in biological sample with high sensitivity and good selectivity. in addition, the presented method was successfully applied for the simultaneous determination of da, aa and ua in urine sample with reliable recovery. this work provides a simple and green route to construct graphene-based electrochemical sensor, which is promising for the simultaneous determination of da, aa and ua. (c) 2013 elsevier bat. all rights reserved.
收录类别SCI
语种英语
公开日期2015-10-27
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/57213]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Yang, La,Liu, Dong,Huang, Jianshe,et al. Simultaneous determination of dopamine, ascorbic acid and uric acid at electrochemically reduced graphene oxide modified electrode[J]. sensors and actuators b-chemical,2014,193(5):166-172.
APA Yang, La,Liu, Dong,Huang, Jianshe,&You,Tianyan.(2014).Simultaneous determination of dopamine, ascorbic acid and uric acid at electrochemically reduced graphene oxide modified electrode.sensors and actuators b-chemical,193(5),166-172.
MLA Yang, La,et al."Simultaneous determination of dopamine, ascorbic acid and uric acid at electrochemically reduced graphene oxide modified electrode".sensors and actuators b-chemical 193.5(2014):166-172.
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