Surface Coordination Polymerization of Ethylene by Hydrozirconation-Immobilized Metallocene

	Surface Coordination Polymerization of Ethylene by Hydrozirconation-Immobilized Metallocene
	Zheng,Jun ; Wang,Yanhui ; Ye,Lin ; Lin,Yichao ; Tang,Tao ; Zhang,Jidong
刊名	macromolecular rapid communications
	2014
卷号	35 期号:13 页码:1198-1203
关键词	SELF-ASSEMBLED MONOLAYERS INITIATED POLYMERIZATION SILICA NANOPARTICLES CARBON NANOTUBES EMULSION POLYMERIZATION OLEFIN POLYMERIZATION LIVING POLYMERIZATION CATALYSTS NANOCOMPOSITES SINGLE
通讯作者	tang,t
英文摘要	hydrozirconation on vinyl-terminated substrates (silicon wafer and nanosilica sphere) is employed as an efficient way for immobilization of zirconocene catalyst through zr-c bonds, which is applied in surface coordination ethylene polymerization producing surface-tethered polyethylene (pe). the formation of zr-c sigma bond induced by hydrozirconation provides an initiator precursor for growing a layer of pe covalently linked onto substrates. the results from sem, afm, and tem show that the surface polymerization is controlled by hydrozirconation. surface pattern or core-shell structure with crystalline pe coating can be formed, when silicon wafer is selectively functionalized with vinyl-groups or vinyl-modified nanosilica is applied. it is believed that hydrozirconation for the synthesis of zirconocene initiator can be a versatile route to prepare polyolefin hybrid materials.
收录类别	SCI
语种	英语
WOS记录号	WOS:000339094900004
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/56175]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zheng,Jun,Wang,Yanhui,Ye,Lin,et al. Surface Coordination Polymerization of Ethylene by Hydrozirconation-Immobilized Metallocene[J]. macromolecular rapid communications,2014,35(13):1198-1203.
APA	Zheng,Jun,Wang,Yanhui,Ye,Lin,Lin,Yichao,Tang,Tao,&Zhang,Jidong.(2014).Surface Coordination Polymerization of Ethylene by Hydrozirconation-Immobilized Metallocene.macromolecular rapid communications,35(13),1198-1203.
MLA	Zheng,Jun,et al."Surface Coordination Polymerization of Ethylene by Hydrozirconation-Immobilized Metallocene".macromolecular rapid communications 35.13(2014):1198-1203.