Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties
Chen, Hui1,2,3; Feng, Yu2; Deng, Guo-Jun1,3; Liu, Zhi-Xiong2,3; He, Yan-Mei2,3; Fan, Qing-Hua2,3
刊名CHEMISTRY-A EUROPEAN JOURNAL
2015-07-27
卷号21期号:31页码:11017-11028
关键词aggregation dendrimers fluorescence multiresponsiveness sol-gel processes supramolecular chemistry
英文摘要A new highly efficient and versatile poly(benzyl ether) dendritic organogelator HPB-G(1) with 2-(2'-hydroxyphenyl) benzoxazole (HPB) at the focal point has been designed and synthesized. HPB-G(1) can form stable organogels toward various apolar and polar organic solvents. Further studies revealed that intermolecular multiple pi-pi stacking interactions are the main driving forces for the formation of the organogels. Notably, dendron HPB-G(1) exhibited a significantly enhanced emission in the gel state in contrast to weak emission in solution. Most interestingly, these dendritic organogels exhibited multiple stimuli-responsive behaviors upon exposure to environmental stimuli, including temperature, sonication, shear stress, and the presence of anions, metal cations, acids/ bases, thus leading to reversible sol-gel phase transitions.
收录类别SCI
语种英语
公开日期2015-10-27
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/27886]  
专题化学研究所_分子识别与功能实验室
作者单位1.Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Coll Chem, Xiangtan 411105, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
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Chen, Hui,Feng, Yu,Deng, Guo-Jun,et al. Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(31):11017-11028.
APA Chen, Hui,Feng, Yu,Deng, Guo-Jun,Liu, Zhi-Xiong,He, Yan-Mei,&Fan, Qing-Hua.(2015).Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties.CHEMISTRY-A EUROPEAN JOURNAL,21(31),11017-11028.
MLA Chen, Hui,et al."Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties".CHEMISTRY-A EUROPEAN JOURNAL 21.31(2015):11017-11028.
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