Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties | |
Chen, Hui1,2,3; Feng, Yu2; Deng, Guo-Jun1,3; Liu, Zhi-Xiong2,3; He, Yan-Mei2,3; Fan, Qing-Hua2,3 | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL
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2015-07-27 | |
卷号 | 21期号:31页码:11017-11028 |
关键词 | aggregation dendrimers fluorescence multiresponsiveness sol-gel processes supramolecular chemistry |
英文摘要 | A new highly efficient and versatile poly(benzyl ether) dendritic organogelator HPB-G(1) with 2-(2'-hydroxyphenyl) benzoxazole (HPB) at the focal point has been designed and synthesized. HPB-G(1) can form stable organogels toward various apolar and polar organic solvents. Further studies revealed that intermolecular multiple pi-pi stacking interactions are the main driving forces for the formation of the organogels. Notably, dendron HPB-G(1) exhibited a significantly enhanced emission in the gel state in contrast to weak emission in solution. Most interestingly, these dendritic organogels exhibited multiple stimuli-responsive behaviors upon exposure to environmental stimuli, including temperature, sonication, shear stress, and the presence of anions, metal cations, acids/ bases, thus leading to reversible sol-gel phase transitions. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/27886] ![]() |
专题 | 化学研究所_分子识别与功能实验室 |
作者单位 | 1.Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Coll Chem, Xiangtan 411105, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Hui,Feng, Yu,Deng, Guo-Jun,et al. Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(31):11017-11028. |
APA | Chen, Hui,Feng, Yu,Deng, Guo-Jun,Liu, Zhi-Xiong,He, Yan-Mei,&Fan, Qing-Hua.(2015).Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties.CHEMISTRY-A EUROPEAN JOURNAL,21(31),11017-11028. |
MLA | Chen, Hui,et al."Fluorescent Dendritic Organogels Based on 2-(2 '-Hydroxyphenyl)benzoxazole: Emission Enhancement and Multiple Stimuli-Responsive Properties".CHEMISTRY-A EUROPEAN JOURNAL 21.31(2015):11017-11028. |
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