Organic base-promoted enantioselective electrophilic cyanation of beta-keto esters by using chiral phase-transfer catalysts

	Organic base-promoted enantioselective electrophilic cyanation of beta-keto esters by using chiral phase-transfer catalysts
	Chen, Min; Huang, Zhi-Tang; Zheng, Qi-Yu
刊名	ORGANIC & BIOMOLECULAR CHEMISTRY
	2015
卷号	13 期号:33 页码:8812-8816
英文摘要	Highly enantioselective cyanation of beta-keto esters using hypervalent iodine(III) as the electrophilic cyanating reagent induced by cinchona alkaloid-based chiral quaternary ammonium salt was demonstrated. Organic bases, especially DMAP, in the chiral phase-transfer catalysis were used to obtain high ees.
收录类别	SCI
语种	英语
公开日期	2015-10-27
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/27729]
专题	化学研究所_分子识别与功能实验室
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Chen, Min,Huang, Zhi-Tang,Zheng, Qi-Yu. Organic base-promoted enantioselective electrophilic cyanation of beta-keto esters by using chiral phase-transfer catalysts[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2015,13(33):8812-8816.
APA	Chen, Min,Huang, Zhi-Tang,&Zheng, Qi-Yu.(2015).Organic base-promoted enantioselective electrophilic cyanation of beta-keto esters by using chiral phase-transfer catalysts.ORGANIC & BIOMOLECULAR CHEMISTRY,13(33),8812-8816.
MLA	Chen, Min,et al."Organic base-promoted enantioselective electrophilic cyanation of beta-keto esters by using chiral phase-transfer catalysts".ORGANIC & BIOMOLECULAR CHEMISTRY 13.33(2015):8812-8816.