QQ客服 官方微博 反馈留言

	Effect of H-2 on selective catalytic reduction of NOx by C3H6 over Ag/Al2O3 and Cu/Al2O3 catalysts
	Zhang Xiuli ; He Hong ; Yu Yunbo
刊名	CHINESE JOURNAL OF CATALYSIS
	2007-02
卷号	28期号:2页码:117-123
关键词	hydrogen silver copper alumina nitrogen oxide selective catalytic reduction in situ diffuse reflectance infrared Fourier transform spectroscopy enolic species isocyanate species
英文摘要	The effect of H-2 on the selective catalytic reduction (SCR) of NO, by C3H6 was investigated over Ag/Al2O3 and Cu/Al2O3 catalysts by steady in situ diffuse reflectance infrared Fourier transform spectroscopy. The presence of H-2 might accelerate the partial oxidation of C3H6 over Ag/Al2O3 to enolic species and acetate. The enolic species can react easily with nitrates to form surface -NCO species. An enhancement of enolic species formation promoted the SCR of NOx over Ag/Al2O3 in the presence of H-2. As for the Cu/Al2O3 catalyst, the addition of H-2 did not influence the partial oxidation of C3H6 to acetate but inhibited apparently the formation of nitrates, and subsequently blocked the reaction between acetate and nitrates to form the key -NCO species. This led to the deactivation of Cu/Al2O3 in the SCR of NO, in the presence of H-2.
WOS记录号	WOS:000244994000007
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/22448]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Zhang Xiuli,He Hong,Yu Yunbo. Effect of H-2 on selective catalytic reduction of NOx by C3H6 over Ag/Al2O3 and Cu/Al2O3 catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(2):117-123.
APA	Zhang Xiuli,He Hong,&Yu Yunbo.(2007).Effect of H-2 on selective catalytic reduction of NOx by C3H6 over Ag/Al2O3 and Cu/Al2O3 catalysts.CHINESE JOURNAL OF CATALYSIS,28(2),117-123.
MLA	Zhang Xiuli,et al."Effect of H-2 on selective catalytic reduction of NOx by C3H6 over Ag/Al2O3 and Cu/Al2O3 catalysts".CHINESE JOURNAL OF CATALYSIS 28.2(2007):117-123.

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。