Determination of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples using hollow fiber-protected liquid-phase microextraction and high performance liquid chromatography

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 环境化学与生态毒理学国家重点实验室

	Determination of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples using hollow fiber-protected liquid-phase microextraction and high performance liquid chromatography
	Peng, Jinfeng ; Lu, Jianxia ; Hu, Xialin ; Liu, Jingfu ; Jiang, Guibin
刊名	MICROCHIMICA ACTA
	2007-04
卷号	158 期号:1 页码:181-186
关键词	hollow fiber-protected liquid-phase microextraction atrazine desethyl atrazine desisopropyl atrazine high-performance liquid chromatography
英文摘要	A new method based on hollow fiberprotected liquid-phase microextraction (LPME) was developed for the simultaneous determination of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples. In LPME, analytes were extracted into 1-octanol immobilized in the micropores of a poly( vinylidene fluoride) porous hollow fiber membrane, and back extracted into the acceptor (4M HCl) filled in the lumen of the hollow fiber. After LPME, the analytes trapped in the acceptor were analyzed with high-performance liquid chromatography after neutralization. The effect of extraction factors such as sample pH, acceptor pH, salinity, extraction time, stirring rate, and humic acid were studied. Under the optimized conditions, the limits of detection and relative standard deviations were respectively in the range of 0.5 - 1.0 mu g L-1 and 3.9 - 4.7% ( n = 5). The proposed method was applied to determine atrazine, desethyl atrazine and desisopropyl atrazine in wastewater and groundwater samples. The three analytes were below the limits of detection, but good relative spiked recoveries over 90.1 +/- 5.9% at 5 mg L-1 spiked level were obtained.
WOS记录号	WOS:000245888000020
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/22433]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Peng, Jinfeng,Lu, Jianxia,Hu, Xialin,et al. Determination of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples using hollow fiber-protected liquid-phase microextraction and high performance liquid chromatography[J]. MICROCHIMICA ACTA,2007,158(1):181-186.
APA	Peng, Jinfeng,Lu, Jianxia,Hu, Xialin,Liu, Jingfu,&Jiang, Guibin.(2007).Determination of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples using hollow fiber-protected liquid-phase microextraction and high performance liquid chromatography.MICROCHIMICA ACTA,158(1),181-186.
MLA	Peng, Jinfeng,et al."Determination of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples using hollow fiber-protected liquid-phase microextraction and high performance liquid chromatography".MICROCHIMICA ACTA 158.1(2007):181-186.