Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules
	Wang, Liang 1; Zhang, Jian 1; Yi, Xianfeng 2; Zheng, Anmin 2; Deng, Feng 2; Chen, Chunyu 1; Ji, Yanyan 1; Liu, Fujian 1; Meng, Xiangju 1; Xiao, Feng-Shou 1
刊名	ACS CATALYSIS
	2015-05-01
卷号	5 期号:5 页码:2727-2734
关键词	phenolic biomolecules hydrodeoxygenation mesoporous zeolite Ru catalyst biomass conversion
英文摘要	Zeolite-based catalysts have been widely used in the conversion of biomass recently, but the catalytic yields of the desired products are strongly limited by the relatively small micropores of zeolite. Here, we reported a hierarchically porous ZSM-5 zeolite with micropore and b-axis-aligned mesopore-supported Ru nanoparticles (Ru/HZSM-5-OM) that are highly efficient for the hydrodeoxygenation of both small and bulky phenolic biomolecules to the corresponding alkanes. Compared with the conventional ZSM-5 zeolite-supported Ru catalyst, the high catalytic activities and alkane selectivities over Ru/HZSM-5-OM are attributed to the abundant exposed acidic sites in HZSM-5-OM with open mesopores. This feature is potentially important for future phenolic bio-oil upgrading.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	SOLID ACID CATALYSTS ; BIO-OIL ; TRIMETHYLPHOSPHINE OXIDE ; CRYSTALLINE ZEOLITE ; BIOMASS CONVERSION ; RANGE ALKANES ; FORMIC-ACID ; P-31 NMR ; HYDRODEOXYGENATION ; WATER
收录类别	SCI
语种	英语
WOS记录号	WOS:000354012200006
公开日期	2015-07-28
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/4741]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Wang, Liang,Zhang, Jian,Yi, Xianfeng,et al. Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules[J]. ACS CATALYSIS,2015,5(5):2727-2734.
APA	Wang, Liang.,Zhang, Jian.,Yi, Xianfeng.,Zheng, Anmin.,Deng, Feng.,...&Xiao, Feng-Shou.(2015).Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules.ACS CATALYSIS,5(5),2727-2734.
MLA	Wang, Liang,et al."Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules".ACS CATALYSIS 5.5(2015):2727-2734.