Effect of Surface Acetylated-Chitin Nanocrystals on Structure and Mechanical Properties of Poly(lactic acid)
Zhang, Qiaoxin1; Wei, Siwen1; Huang, Jin2,3; Feng, Jiwen4; Chang, Peter R.5
刊名JOURNAL OF APPLIED POLYMER SCIENCE
2014-01-15
卷号131期号:2
关键词biodegradable composites mechanical properties polysaccharides chitin nanocrystal poly(lactic acid)
英文摘要In this work, the miscibility between chitin nanocrystals (ChNs) and poly(lactic acid) (PLA) was expected to be improved by surface acetylation of ChN. The reaction of acetic anhydride onto the ChN surface was confirmed by FTIR and C-13 NMR, while XRD and TEM proved the crystalline structure and rod-like morphology were maintained. The acetylated ChN (AChN) was incorporated into a PLA matrix by solution blending, and resulted in an increase of tensile strength and Young's modulus and they reached to the maximum value as 45 and 37% higher than neat PLA film, respectively, with the loading level of AChN reaching to 4 wt %. The enhancement could be attributed to that acetylation improved dispersion of AChN in the PLA matrix and interfacial adhesion between AChN and PLA. The performances of the nanocomposites based on PLA and chitin nanocrystals derived from renewable resources have good potential for industrial applications. (C) 2013 Wiley Periodicals, Inc.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]REINFORCED POLYLACTIC ACID ; CELLULOSE NANOFIBERS ; MICROFIBRILLATED CELLULOSE ; BARRIER PROPERTIES ; COMPOSITES ; PLA ; STARCH ; BIODEGRADATION ; NANOCOMPOSITE ; WHISKERS
收录类别SCI
语种英语
WOS记录号WOS:000336256000054
公开日期2015-07-14
内容类型期刊论文
源URL[http://ir.wipm.ac.cn/handle/112942/1407]  
专题武汉物理与数学研究所_磁共振应用研究部
作者单位1.Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
2.Wuhan Univ Technol, Coll Chem Engn, Wuhan 430070, Peoples R China
3.S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
4.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
5.Agr & Agri Food Canada, BioProd & Bioproc Natl Sci Program, Saskatoon, SK S7N 0X2, Canada
推荐引用方式
GB/T 7714
Zhang, Qiaoxin,Wei, Siwen,Huang, Jin,et al. Effect of Surface Acetylated-Chitin Nanocrystals on Structure and Mechanical Properties of Poly(lactic acid)[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2014,131(2).
APA Zhang, Qiaoxin,Wei, Siwen,Huang, Jin,Feng, Jiwen,&Chang, Peter R..(2014).Effect of Surface Acetylated-Chitin Nanocrystals on Structure and Mechanical Properties of Poly(lactic acid).JOURNAL OF APPLIED POLYMER SCIENCE,131(2).
MLA Zhang, Qiaoxin,et al."Effect of Surface Acetylated-Chitin Nanocrystals on Structure and Mechanical Properties of Poly(lactic acid)".JOURNAL OF APPLIED POLYMER SCIENCE 131.2(2014).
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