Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates
	Chen, Peng 1; Li, Jiyang 1; Xu, Jun 2; Duan, Fangzheng 1; Deng, Feng 2; Xu, Ruren 1
刊名	SOLID STATE SCIENCES
	2009-03-01
卷号	11 期号:3 页码:622-627
关键词	Aluminophosphate Monomer H-bond NMR Solvothermal synthesis Cobalt complex
通讯作者	Li, JY (reprint author), Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China.
英文摘要	A new zero-dimensional (0D) aluminophosphate monomer [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)] (H3PO4)(4) (designated AlPO-CJ38) with Al/P ratio of 1/6 has been solvothermally prepared by using racemic cobalt complex dl-Co(en)(3)Cl-3 as the template. The Al atom is octahedrally linked to six P atoms via bridging oxygen atoms, forming a unique [Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](6-) monomer. Notably, there exists intramolecular symmetrical O center dot center dot center dot H center dot center dot center dot O bonds, which results in pseudo-4-rings stabilized by the strong H-bonding interactions. The structure is also featured by the existence of four different types of monophosphates that have been confirmed by P-31 NMR and H-1 NMR spectra. The crystal data are as follows: AlPO-CJ38, [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4), M = 1476.33, monoclinic, C2/c (No. 15), a = 36.028(7) angstrom, b = 8.9877(18) angstrom, c = 16.006(3) angstrom, beta = 100.68(3)degrees, U = 5093.2(18) angstrom(3), Z = 4, R-1 = 0.0509 (I > 2 sigma(I)) and wR(2) = 0.1074 (all data). CCDC number 689491. (C) 2008 Elsevier Masson SAS. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Physics, Condensed Matter
研究领域[WOS]	Chemistry ; Physics
关键词[WOS]	OPEN FRAMEWORK ALUMINOPHOSPHATE ; NEUTRON-DIFFRACTION ; HYDROGEN-BOND ; ALUMINUM PHOSPHATE ; CRYSTAL-STRUCTURES ; X-RAY ; LAYERED ALUMINOPHOSPHATE ; METAL PHOSPHATES ; MOLECULAR-SIEVE ; COMPLEX CATIONS
收录类别	SCI
语种	英语
WOS记录号	WOS:000264644800004
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/2267]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Chen, Peng,Li, Jiyang,Xu, Jun,et al. Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates[J]. SOLID STATE SCIENCES,2009,11(3):622-627.
APA	Chen, Peng,Li, Jiyang,Xu, Jun,Duan, Fangzheng,Deng, Feng,&Xu, Ruren.(2009).Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates.SOLID STATE SCIENCES,11(3),622-627.
MLA	Chen, Peng,et al."Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates".SOLID STATE SCIENCES 11.3(2009):622-627.