Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 2011年以前论文发表（包括2011年）

	Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties
	Rong, Cheng 2; Yu, Zhiwu 1; Wang, Qiang 1; Zheng, Shou-Tian 2; Pan, Chun-Yang 2; Deng, Feng 1; Yang, Guo-Yu 2
刊名	INORGANIC CHEMISTRY
	2009-04-20
卷号	48 期号:8 页码:3650-3659
通讯作者	Deng, F (reprint author), Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China.
英文摘要	Five aluminoborates Al[B(5)O(10)]center dot H(2)dab center dot 2H(2)O (1), [Al(B(4)O(9))(BO)]center dot H(2)en (2), [Al(B(4)O9)(BO)]center dot H(2)dap (3), K(2)Al[B(5)O(10)]center dot 4H(2)O (4), and (NH(4))(2)Al[B(5)O(10)]center dot 4H(2)O (5) have been synthesized under hydrothermal conditions and characterized by means of elemental analysis, IR, TG analysis, MAS NMR, UV-vis and fluorescence spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction, and NLO determination. The structure 1 comprises of AlO(4) tetrahedra and B(5)O(10) clusters and contains 12-, 11-, and 8-MR 3D-intersecting channels with a CrB(4) topological net. Structures 2 and 3 are both constructed from the same AlB(5)O(13) clusters and exhibit a six-connected framework with 4(12)6(3) topology. Structures 4 and 5 are isomorphous and are composed of AlO(4) tetrahedra and B(5)O(10) clusters that possess odd 11-MR channels and 8-MR helical channels. Structures 2-5 crystallized in an acentric structure and presented good SHG properties. UV-vis spectral investigation indicates that they are wide-band-gap semiconductors. The electronic structure calculations for the compounds also have been performed.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Inorganic & Nuclear
研究领域[WOS]	Chemistry
关键词[WOS]	NONLINEAR-OPTICAL CRYSTAL ; FUNDAMENTAL BUILDING-BLOCKS ; BORON-ALUMINUM OXOCHLORIDE ; HIGH-PRESSURE PREPARATION ; SHARING BO4 TETRAHEDRA ; HELICAL CHANNELS ; BORATE MINERALS ; BORIC-ACID ; BOROGERMANATE ; CLUSTERS
收录类别	SCI
语种	英语
WOS记录号	WOS:000265166300038
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/2236]
专题	武汉物理与数学研究所_2011年以前论文发表（包括2011年）
作者单位	1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
推荐引用方式 GB/T 7714	Rong, Cheng,Yu, Zhiwu,Wang, Qiang,et al. Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties[J]. INORGANIC CHEMISTRY,2009,48(8):3650-3659.
APA	Rong, Cheng.,Yu, Zhiwu.,Wang, Qiang.,Zheng, Shou-Tian.,Pan, Chun-Yang.,...&Yang, Guo-Yu.(2009).Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties.INORGANIC CHEMISTRY,48(8),3650-3659.
MLA	Rong, Cheng,et al."Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties".INORGANIC CHEMISTRY 48.8(2009):3650-3659.