Targeted synthesis of an electroactive organic framework | |
Ben, Teng3; Shi, Kang1,2; Cui, Yan3; Pei, Cuiying3; Zuo, Yang1,2; Guo, Han3; Zhang, Daliang3; Xu, Jun4; Deng, Feng4; Tian, Zhongqun1,2 | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY |
2011 | |
卷号 | 21期号:45页码:18208-18214 |
产权排序 | 第一 |
英文摘要 | A new strategy for targeted design and synthesis of an electroactive microporous organic molecular sieve (JUC-Z2) is described. Experiment demonstrated that such a targeted synthesis approach to achieve phenyl-phenyl coupling was a controllable process and predominately generated two-dimensional polymer sheets, significantly different from the traditional chemical or electrochemical oxidation methods to prepare conducting polymers. Successive self-assembly leads to a lamellar organic framework comprised of stacked polymer sheets with an hcb topology. JUC-Z2 was found to have a well-defined uniform micropore distribution (similar to 1.2 nm), a large surface area (BET = 2081 m(2) g(-1)) and high physicochemical stability (> 440 degrees C). After doping with I(2), JUC-Z2 exhibits typical p-type semiconductive properties. As the first example of an electroactive organic framework, JUC-Z2 possesses a unique ability of electrochemical ion recognition, arising from the synergistic function of the uniform micropores and the N-atom redox site. |
学科主题 | 波谱学 |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Materials Science |
关键词[WOS] | HIGH-SURFACE-AREA ; CONJUGATED MICROPOROUS POLYMERS ; ELECTROLUMINESCENT DEVICES ; HETEROGENEOUS CATALYSIS ; HYDROGEN STORAGE ; NETWORKS ; POLYANILINE ; DESIGN ; CRYSTALLINE ; TEMPLATES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000296735900012 |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/1894] |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2.Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 3.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 4.Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan, Peoples R China |
推荐引用方式 GB/T 7714 | Ben, Teng,Shi, Kang,Cui, Yan,et al. Targeted synthesis of an electroactive organic framework[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(45):18208-18214. |
APA | Ben, Teng.,Shi, Kang.,Cui, Yan.,Pei, Cuiying.,Zuo, Yang.,...&Qiu, Shilun.(2011).Targeted synthesis of an electroactive organic framework.JOURNAL OF MATERIALS CHEMISTRY,21(45),18208-18214. |
MLA | Ben, Teng,et al."Targeted synthesis of an electroactive organic framework".JOURNAL OF MATERIALS CHEMISTRY 21.45(2011):18208-18214. |
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