Enhanced luminescence properties of monodisperse trioctylphosphine oxide-capped Nd3+-doped LaF3 nanorods without OH groups | |
Cui, Xiaoxia1; Guo, Haitao1; Hou, Chaoqi1; Gao, Fei1; Wang, Zhongyue2; Wei, Wei1,2; Peng, Bo1,2 | |
刊名 | colloids and surfaces a-physicochemical and engineering aspects |
2013-09-05 | |
卷号 | 436页码:386-391 |
关键词 | LaF3:Nd nanorods Thermolysis method TOPO Surface modification |
英文摘要 | nd3+-doped laf3 nanorods without -oh groups were synthesized via a simple thermolysis method in trioctylphosphine oxide (topo) solvent. ftir spectrum indicates that topo molecules have been coordinated to laf3:nd nanorods surface, which reduce the number of -oh groups on the nanoparticles surface effectively. the structure and morphology of as-synthesized nanorods were characterized. the possible grow mechanism of laf3:nd nanorods has been also discussed in detail. the topo capped laf3:nd nanoparticles preferentially grow along the <0 0 0 1> orientation under high temperature. based on the absorption spectra and judd-ofelt theory, higher value of emission cross-section for f-4(3/2)-> i-4(11/2) transition of nd3+ was calculated to be 3.22 x 10(-20) cm(2). the strong fluorescence intensity of laf3:nd nanorods in chloroform demonstrates that these nanorods are promising luminescence materials. (c) 2013 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | rare-earth fluoride ; cdse nanocrystals ; nanoparticles ; fluorescence ; complex ; ions |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:000326416900050 |
公开日期 | 2015-06-30 |
内容类型 | 期刊论文 |
源URL | [http://ir.opt.ac.cn/handle/181661/23304] |
专题 | 西安光学精密机械研究所_先进光电与生物材料研发中心 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Shaanxi, Peoples R China 2.Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210003, Peoples R China |
推荐引用方式 GB/T 7714 | Cui, Xiaoxia,Guo, Haitao,Hou, Chaoqi,et al. Enhanced luminescence properties of monodisperse trioctylphosphine oxide-capped Nd3+-doped LaF3 nanorods without OH groups[J]. colloids and surfaces a-physicochemical and engineering aspects,2013,436:386-391. |
APA | Cui, Xiaoxia.,Guo, Haitao.,Hou, Chaoqi.,Gao, Fei.,Wang, Zhongyue.,...&Peng, Bo.(2013).Enhanced luminescence properties of monodisperse trioctylphosphine oxide-capped Nd3+-doped LaF3 nanorods without OH groups.colloids and surfaces a-physicochemical and engineering aspects,436,386-391. |
MLA | Cui, Xiaoxia,et al."Enhanced luminescence properties of monodisperse trioctylphosphine oxide-capped Nd3+-doped LaF3 nanorods without OH groups".colloids and surfaces a-physicochemical and engineering aspects 436(2013):386-391. |
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