Preparation of porous silicon/carbon microspheres as high performance anode materials for lithium ion batteries | |
Ren, Wenfeng1,2; Zhang, Zailei1; Wang, Yanhong1; Tan, Qiangqiang1; Zhong, Ziyi3; Su, Fabing1 | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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2015 | |
卷号 | 3期号:11页码:5859-5865 |
关键词 | HIGH-CAPACITY SCALABLE SYNTHESIS ELECTROCHEMICAL PROPERTIES GRAPHITE MICROSPHERES CARBON NANOTUBES NANOPARTICLES COMPOSITE ELECTRODES LITHIATION NANOSHEETS |
ISSN号 | 2050-7488 |
通讯作者 | Tan, QQ (reprint author), Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China. |
英文摘要 | We report the preparation of porous silicon/carbon microspheres (GPSCMs) by the ball milling and spray drying methods followed by carbonization and chemical vapor deposition processes, in which, the waste fine graphitized needle coke and silicon nanoparticles were employed as the carbon and silicon sources respectively, and sucrose as the binder. The samples were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, nitrogen adsorption, thermogravimetric analysis, and Raman spectroscopy. It was found that GPSCMs had spherical sizes of 8-30 mu m and surface areas between 20 and 90 m(2) g(-1). When used as the anode materials for lithium ion batteries, the average charge capacity was 589 mA h g(-1) at a current density of 50 mA g(-1), much higher than that of the commercial graphite microspheres (GMs). Furthermore, GPSCMs exhibited much better rate performance than the commercial GMs, making them promising for use as the next generation anode materials in lithium ion batteries. |
学科主题 | Chemistry ; Energy & Fuels ; Materials Science |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
关键词[WOS] | HIGH-CAPACITY ; SCALABLE SYNTHESIS ; ELECTROCHEMICAL PROPERTIES ; GRAPHITE MICROSPHERES ; CARBON NANOTUBES ; NANOPARTICLES ; COMPOSITE ; ELECTRODES ; LITHIATION ; NANOSHEETS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000350886600015 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/13843] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.ASTAR, Inst Chem Engn & Sci, Jurong Isl 627833, Singapore |
推荐引用方式 GB/T 7714 | Ren, Wenfeng,Zhang, Zailei,Wang, Yanhong,et al. Preparation of porous silicon/carbon microspheres as high performance anode materials for lithium ion batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(11):5859-5865. |
APA | Ren, Wenfeng,Zhang, Zailei,Wang, Yanhong,Tan, Qiangqiang,Zhong, Ziyi,&Su, Fabing.(2015).Preparation of porous silicon/carbon microspheres as high performance anode materials for lithium ion batteries.JOURNAL OF MATERIALS CHEMISTRY A,3(11),5859-5865. |
MLA | Ren, Wenfeng,et al."Preparation of porous silicon/carbon microspheres as high performance anode materials for lithium ion batteries".JOURNAL OF MATERIALS CHEMISTRY A 3.11(2015):5859-5865. |
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