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The microstructure and ferroelectricity of BiScO3-PbTiO3 nanoceramics at morphotropic phase boundaries
Zhang, SP ; Wang, XH ; Zhu, JL ; Jin, CQ ; Gong, HL ; Li, LT
刊名SCRIPTA MATERIALIA
2014
卷号82页码:45
关键词Ferroelectric Nanoceramics MPB Microstructures
ISSN号1359-6462
通讯作者Wang, XH (reprint author), Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China.
中文摘要Dense (1 - x)BiScO3-xPbTiO(3) nanoceramics with morphotropic phase boundaries and an average grain size of 11 nm were prepared. Synchrotron X-ray diffraction studies revealed that tetragonal and monoclinic phases coexist, and the grain boundary regions could be modeled as a paraelectric cubic phase. The grain boundary regions possessed complicated stress and electric fields. The polarization switching became more difficult under electric field due to the restriction and screening effect of grain boundary regions. The nanoceramics retained ferroelectricity with d(33)* = 292.9 +/- 29.8 pm V-1 and d(33) = 19.8 pC N-1 (c) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
资助信息Ministry of Sciences and Technology of China through the National Basic Research Program of China (973 Program) [2009CB623301]; National Natural Science Foundation of China for Creative Research Groups [51221291]; National Natural Science Foundation of China for Distinguished Young Scholars [50625204]; National Natural Science Foundation of China [51272123]; DOE-NNSA [DE-NA0001974]; DOE-BES [DE-FG02-99ER45775]; NSF
语种英语
公开日期2015-04-14
内容类型期刊论文
源URL[http://ir.iphy.ac.cn/handle/311004/59735]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Zhang, SP,Wang, XH,Zhu, JL,et al. The microstructure and ferroelectricity of BiScO3-PbTiO3 nanoceramics at morphotropic phase boundaries[J]. SCRIPTA MATERIALIA,2014,82:45.
APA Zhang, SP,Wang, XH,Zhu, JL,Jin, CQ,Gong, HL,&Li, LT.(2014).The microstructure and ferroelectricity of BiScO3-PbTiO3 nanoceramics at morphotropic phase boundaries.SCRIPTA MATERIALIA,82,45.
MLA Zhang, SP,et al."The microstructure and ferroelectricity of BiScO3-PbTiO3 nanoceramics at morphotropic phase boundaries".SCRIPTA MATERIALIA 82(2014):45.
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