A way to realize controllable preparation of active nickel oxide supported nano-Au catalyst for CO oxidation | |
Zhang CM(张成明)1,2; Cui XJ(崔新江)1![]() ![]() ![]() ![]() | |
刊名 | Applied Catalysis A: General
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2014 | |
卷号 | 473页码:7-12 |
关键词 | Chlorine concentration CO oxidation Nano-Au catalyst Heterogeneous catalyst Controllable preparation |
ISSN号 | 0926-860X |
通讯作者 | 石峰 |
英文摘要 | It was generally accepted that the total elimination of chlorine is favorable to build active supportednano-gold catalysts if chlorine-containing precursors was used especially for the total oxidation of CO.Here a series of Au/NiOx catalysts were prepared with co-precipitation method by tracing the chlorineconcentration in the washing step and tested by the total oxidation of CO. It was revealed that Au/NiOxcatalysts prepared from aqueous solutions with 4–8 ppm chlorine can be active catalysts and the temper-ature for CO total oxidation was <0◦C. The catalytic activity dropped sharply if the chlorine concentrationwas <4 ppm or >8 ppm. The catalysts were characterized by XRD, XPS, BET, TEM, HAADF-STEM and EXAFS,and the catalyst structures were explored. The different structures of the catalysts should be responsiblefor the activity variation and it was caused by the washing operation or the presence of different amountsof chlorine. Although active Au/NiOx catalysts can be obtained by tracing chlorine concentration, the roleof chlorine in the fabrication of active nano-gold catalyst was still unclear. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China(21073208);the CAS |
语种 | 英语 |
WOS记录号 | WOS:000333856300002 |
公开日期 | 2015-01-15 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/7117] ![]() |
专题 | 兰州化学物理研究所_绿色化学研究发展中心 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Ctr Multidisciplinary Res, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang CM,Cui XJ,Yang HM,et al. A way to realize controllable preparation of active nickel oxide supported nano-Au catalyst for CO oxidation[J]. Applied Catalysis A: General,2014,473:7-12. |
APA | Zhang CM,Cui XJ,Yang HM,Zheng LR,Deng YQ,&Shi F.(2014).A way to realize controllable preparation of active nickel oxide supported nano-Au catalyst for CO oxidation.Applied Catalysis A: General,473,7-12. |
MLA | Zhang CM,et al."A way to realize controllable preparation of active nickel oxide supported nano-Au catalyst for CO oxidation".Applied Catalysis A: General 473(2014):7-12. |
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