Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock
Li Q(李欠)1; Wang ZZ(王振忠)1,2; Xu J(徐健)1,2; Yue Y(岳莹)1; Shao SJ(邵士俊)1
刊名RSC Advances
2014
卷号4期号:65页码:34470-34473
ISSN号2046-2069
通讯作者邵士俊
英文摘要

Calix[4]pyrrole based anion receptors 1 and 2 have been synthesized. The recognition and sensing process has been studied by UV-vis absorption and partial 1H NMR titration experiments. Receptor 1 could act as a colorimetric sensor for fluoride anions, and receptor 2 could recognize F- and AcO- anions in DMSO solvent. Moreover, this type of sensing behaviour could successfully mimic a molecular level keypad lock stimulated by the two sequential chemical inputs (AcO- and F-), which has the potential for application in security devices.

学科主题分析化学与药物化学
收录类别SCI
资助信息the National Natural Science Foundation of China (20972170;21275150);the Funds for Distinguished Young Scientists of Gansu (1210RJDA013);the Natural Science Foundation of Gansu province (1107RJYA069)
语种英语
WOS记录号WOS:000341287500034
公开日期2014-10-22
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/6579]  
专题兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
作者单位1.Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
2.University of Chinese Academy of Sciences, Beijing 100039, P. R. China
推荐引用方式
GB/T 7714
Li Q,Wang ZZ,Xu J,et al. Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock[J]. RSC Advances,2014,4(65):34470-34473.
APA Li Q,Wang ZZ,Xu J,Yue Y,&Shao SJ.(2014).Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock.RSC Advances,4(65),34470-34473.
MLA Li Q,et al."Recognition and sensing of AcO- and F- using a calix[4]pyrrole-derived hydrazone: a potential molecular keypad lock".RSC Advances 4.65(2014):34470-34473.
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