Supercapacitor, known as an important energy storage device, is also a critical component for next generation of hydrogen fuel cell vehicles. In this study, we report a novel route for synthesis of three-dimensional Ni(OH)₂/graphene/nickel foam electrode by electrochemical depositing Ni(OH)₂ nanoflakes on graphene network grown on nickel foam current collector and explore its applications in supercapacitors. The resulting binder-free Ni(OH)₂/graphene/nickel foam electrode exhibits excellent supercapacitor performance with a specific capacitance of 2161 F/g at a current density of 3 A/g. Even as the current density reaches up to 60 A/g, it still remains a high capacitance of 1520 F/g, which is much higher than that of Ni(OH)₂/nickel foam electrode. The enhanced rate capability performance of Ni(OH)₂/graphene/nickel foam electrode is closely related to the presence of highly conductive graphene layer on nickel foam, which can remarkably boost the chargetransfer process at electrolyteeelectrode interface. The three-dimensional graphene/nickel foam substrate also significantly improves the electrochemical cycling stability of the electrodeposited Ni(OH)₂ film because of the strong adhesion between graphene film and electrodeposited Ni(OH)₂ nanoflakes. Results of this study provide an alternative pathway to improve the rate capability and cycling stability of Ni(OH)₂ nanostructure electrode and offer a great promise for its applications in supercapacitors.