Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes
	Zhang CY(张春艳)1,2 ; Liu JH(刘建华)1 ; Xia CG(夏春谷)1 ; Liu JH(刘建华); Xia CG(夏春谷)
刊名	Organic & Biomolecular Chemistry
	2014
卷号	12 期号:47 页码:9702-9706
ISSN号	1477-0520
通讯作者	刘建华 ; 夏春谷
英文摘要	A series of aryl-palladium-NHC compounds was prepared according to the reported methods and their catalytic activity in the carbonylation of aryl iodides to synthesize alpha-keto amides and alkynones was examined. These practical aryl-palladium-NHC complexes have shown highly efficient catalyzed carbonylation and Sonogashira carbonylation reactions, with high turnover number in synthesis of alpha-keto amides (TON = 4300) and in synthesis of alkynones (TON = 980).
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (21373248;21133011;21073209)
语种	英语
WOS记录号	WOS:000345066100026
公开日期	2014-11-27
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/6814]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Liu JH(刘建华); Xia CG(夏春谷)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Zhang CY,Liu JH,Xia CG,et al. Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes[J]. Organic & Biomolecular Chemistry,2014,12(47):9702-9706.
APA	Zhang CY,Liu JH,Xia CG,刘建华,&夏春谷.(2014).Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes.Organic & Biomolecular Chemistry,12(47),9702-9706.
MLA	Zhang CY,et al."Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes".Organic & Biomolecular Chemistry 12.47(2014):9702-9706.