Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes

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	Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes
	Wang Y(汪妍)1; Yang XL(杨晓龙)2 ; Zhang CY(张春艳)2 ; Yu JQ(于健强)1 ; Liu JH(刘建华)2 ; Xia CG(夏春谷)2 ; Liu JH(刘建华); Yu JQ(于健强)
刊名	Advanced Synthesis & Catalysis
	2014
卷号	356 期号:11-12 页码:2539-2546
关键词	double carbonylation N-heterocyclic carbene-amine palladium complexes phosphine-free reaction water-soluble complexes
ISSN号	1615-4150
通讯作者	于健强 ; 刘建华
英文摘要	The water-insoluble and water-soluble Nheterocyclic carbene (NHC)–amine palladium complexes, Ipr-Pd(deba)Cl and SO₃-Ipr-Pd(deba)Cl, were synthesized. Both catalysts exhibit excellent activity in the phosphine-free double carbonylation of aryl iodides with amines to produce a-keto amides. Moreover, as the water-soluble catalyst exhibits significant compatibility in the aqueous phase with the activities of different Pd-NHC complexes, we conclude that the intramolecular amine ligand strongly affects the selectivity of the products in double carbonylation reaction and serves as an alternative of phosphine ligands.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (No. 21073209;No. 21373248;No. 21133011)
语种	英语
WOS记录号	WOS:000340567100019
公开日期	2014-10-16
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/6524]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_清洁能源化学与材料实验室
通讯作者	Liu JH(刘建华); Yu JQ(于健强)
作者单位	1.Chinese Acad Sci, Lab Clean Energy Chem & Mat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Wang Y,Yang XL,Zhang CY,et al. Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes[J]. Advanced Synthesis & Catalysis,2014,356(11-12):2539-2546.
APA	Wang Y.,Yang XL.,Zhang CY.,Yu JQ.,Liu JH.,...&于健强.(2014).Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes.Advanced Synthesis & Catalysis,356(11-12),2539-2546.
MLA	Wang Y,et al."Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes".Advanced Synthesis & Catalysis 356.11-12(2014):2539-2546.