NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides

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	NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides
	Zheng SZ(郑书展); Wang Y(汪妍); Zhang CY(张春艳); Liu JH(刘建华); Xia CG(夏春谷); Xia CG(夏春谷); Liu JH(刘建华)
刊名	Applied Organometallic Chemistry
	2014
卷号	28 期号:1 页码:48-53
关键词	N-heterocyclic carbene palladium complexes double carbonylation aryl iodides α-keto amides
ISSN号	0268-2605
通讯作者	刘建华 ; 夏春谷
英文摘要	A series of palladium–NHC compounds were prepared and their catalytic activity in the double carbonylation of aryl iodides to synthesize α-keto amides were examined. Palladium complexes bearing mixed NHC–phosphine exhibited high efficiency for the double carbonylation reaction. The effects of different solvents, base, temperature, carbon monoxide (CO), pressure, various amine and aryl iodides were investigated. Both electron-rich and electron-deficient aryl iodides afforded the corresponding substituted α-keto amides in moderate to good yields. A possible mechanism was also proposed.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (21073209;21133011)
语种	英语
WOS记录号	WOS:000328226600007
公开日期	2014-10-16
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/6522]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Liu JH(刘建华)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Zheng SZ,Wang Y,Zhang CY,et al. NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides[J]. Applied Organometallic Chemistry,2014,28(1):48-53.
APA	Zheng SZ.,Wang Y.,Zhang CY.,Liu JH.,Xia CG.,...&刘建华.(2014).NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides.Applied Organometallic Chemistry,28(1),48-53.
MLA	Zheng SZ,et al."NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides".Applied Organometallic Chemistry 28.1(2014):48-53.