Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)
	Wang, Zheng; Zhang, Min; Pan, Shilie; Yang, Zhihua; Zhang, Hui; Zhang, Bingbing; Wang, Ying; Kang, Jing; Lin, Xiaoxia
刊名	NEW JOURNAL OF CHEMISTRY
	2014
卷号	38 期号:7 页码:3035-3041
ISSN号	1144-0546
通讯作者	Zhang, M
英文摘要	The structures of three borates with isolated BO3 groups, RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4), are determined from single crystal diffraction data for the first time. The introduction of small cations (Mg2+ and Zn2+) with strong bonding can prevent the formation of the B-O network effectively, and is beneficial to obtain the isolated BO3 groups. Moreover, the cationic skeletons composed of small cations significantly affect the arrangement of isolated BO3 groups. Thermal analysis, infrared and UV-Vis-NIR diffuse reflectance spectroscopy, and electronic band structure calculations were performed for the reported materials.
收录类别	SCI
WOS记录号	WOS:000338117900044
公开日期	2014-11-11
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/3817]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Zheng,Zhang, Min,Pan, Shilie,et al. Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)[J]. NEW JOURNAL OF CHEMISTRY,2014,38(7):3035-3041.
APA	Wang, Zheng.,Zhang, Min.,Pan, Shilie.,Yang, Zhihua.,Zhang, Hui.,...&Lin, Xiaoxia.(2014).Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4).NEW JOURNAL OF CHEMISTRY,38(7),3035-3041.
MLA	Wang, Zheng,et al."Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)".NEW JOURNAL OF CHEMISTRY 38.7(2014):3035-3041.