An alternative total synthesis of solamargine

	An alternative total synthesis of solamargine
	Wei GuoHua ; Wei DongBin ; Du YuGuo
刊名	Chemistry
	2012
卷号	55 期号:7 页码:1247-1251
关键词	solasodine natural products solamargine glycosides
ISSN号	1674-7291
中文摘要	Solamargine, (25R)-3 beta-{O-alpha-l-rhamnopyranosyl-(1 -> 2)-[O-alpha-l-rhamnopyranosyl-(1 -> 4)]-beta-d-glucopyranosyloxy}-22 alpha-N-spirosol-5-ene, isolated from the berries of solanum aculeastrum, has been synthesized in 26.8% overall yield. First glycosylation before N-cyclization significantly facilitated synthesis of the desired molecule. We anticipate that this work will provide a new approach to access solamargine and its diversified analogues.
WOS记录号	WOS:000306070500007
公开日期	2014-11-27
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/8027]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Wei GuoHua,Wei DongBin,Du YuGuo. An alternative total synthesis of solamargine[J]. Chemistry,2012,55(7):1247-1251.
APA	Wei GuoHua,Wei DongBin,&Du YuGuo.(2012).An alternative total synthesis of solamargine.Chemistry,55(7),1247-1251.
MLA	Wei GuoHua,et al."An alternative total synthesis of solamargine".Chemistry 55.7(2012):1247-1251.