Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids

	Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids
	Liu, Bing 1,2; Zhang, Zehui 1,2; Zhao, Zongbao Kent 3,4
刊名	chemical engineering journal
	2013-01-15
卷号	215 页码:517-521
关键词	Biomass Cellulose Zirconium chloride 5-Hydroxymethylfurfural Ionic liquids Microwave irradiation
通讯作者	赵宗保 ; 张泽会
产权排序	待补充
合作状况	英
英文摘要	microwave-assisted direct conversion of cellulose into hmf in ionic liquids catalyzed by zrcl4 has been investigated in search of an efficient and environment-friendly process. firstly, some representative metal chlorides were used to catalyze the conversion of glucose into hmf, and it was demonstrated that zrcl4 was superior to other catalysts. then direct conversion of cellulose into hmf was catalyzed by zrcl4 under microwave irradiation (mi). under optimal conditions, a high hmf yield up to 51.4% was obtained from cellulose in 3.5 mm under mi at 400w. controllable experiments indicated that both ionic liquids, mi and zrcl4 showed synergetic effects on the efficient conversion of cellulose into hmf. this work provides a meaningful method for the conversion of carbohydrates into fine chemicals. (c) 2012 elsevier b.v. all rights reserved.
学科主题	物理化学
WOS标题词	science & technology ; technology
类目[WOS]	engineering, environmental ; engineering, chemical
研究领域[WOS]	engineering
关键词[WOS]	acid ; hydrolysis ; efficient ; glucose ; imidazolium ; chemistry ; biomass ; water
收录类别	SCI
资助信息	2，3
原文出处	521
语种	英语
WOS记录号	WOS:000316032100064
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119606]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.South Cent Univ Nationalities, Coll Chem & Mat Sci, Key Lab Catalysis & Mat Sci State Ethn Affairs Co, Wuhan 430074, Peoples R China 2.South Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Liu, Bing,Zhang, Zehui,Zhao, Zongbao Kent. Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids[J]. chemical engineering journal,2013,215:517-521.
APA	Liu, Bing,Zhang, Zehui,&Zhao, Zongbao Kent.(2013).Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids.chemical engineering journal,215,517-521.
MLA	Liu, Bing,et al."Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids".chemical engineering journal 215(2013):517-521.