Dimethyl Ether Carbonylation to Methyl Acetate over Nanosized Mordenites

	Dimethyl Ether Carbonylation to Methyl Acetate over Nanosized Mordenites
	Xue, Huifu 1; Huang, Xiumin 1; Ditzel, Evert 2; Zhan, Ensheng 1; Ma, Meng 1; Shen, Wenjie 1
刊名	industrial & engineering chemistry research
	2013-08-21
卷号	52 期号:33 页码:11510-11515
通讯作者	申文杰
产权排序	待补充
合作状况	英
英文摘要	nanosized mordenites were found to show significantly enhanced reaction efficiency in dimethyl ether (dme) carbonylation to methyl acetate (ma) because of a greatly facilitated diffusion process. copper incorporation into the channels of the nanosized mordenites further promoted the reaction rate, selectivity, and stability. moreover, upon the addition of a small amount of h-2 (5-19 vol %) to the feed gas, deactivation was suppressed during dme carbonylation, whereas the catalyst stability and rate of formation of ma increased.
学科主题	物理化学
WOS标题词	science & technology ; technology
类目[WOS]	engineering, chemical
研究领域[WOS]	engineering
关键词[WOS]	acid sites ; selective carbonylation ; zsm-5 nanocrystals ; bronsted acidity ; molecular-sieve ; h-mordenite ; zeolites ; methanol ; catalysts ; performance
收录类别	SCI
资助信息	1，1
原文出处	11515
语种	英语
WOS记录号	WOS:000323536000028
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119559]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England
推荐引用方式 GB/T 7714	Xue, Huifu,Huang, Xiumin,Ditzel, Evert,et al. Dimethyl Ether Carbonylation to Methyl Acetate over Nanosized Mordenites[J]. industrial & engineering chemistry research,2013,52(33):11510-11515.
APA	Xue, Huifu,Huang, Xiumin,Ditzel, Evert,Zhan, Ensheng,Ma, Meng,&Shen, Wenjie.(2013).Dimethyl Ether Carbonylation to Methyl Acetate over Nanosized Mordenites.industrial & engineering chemistry research,52(33),11510-11515.
MLA	Xue, Huifu,et al."Dimethyl Ether Carbonylation to Methyl Acetate over Nanosized Mordenites".industrial & engineering chemistry research 52.33(2013):11510-11515.