Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose

	Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose
	Li, Guangyi 1,2; Li, Ning 1; Yang, Jinfan 1,2; Wang, Aiqin 1; Wang, Xiaodong 1; Cong, Yu 1; Zhang, Tao 1
刊名	bioresource technology
	2013-04-01
卷号	134 页码:66-72
关键词	Lignocellulose Diesel Hydroxyalkylation/alkylation Hydrodeoxygenation Ni-WxC/C
ISSN号	0960-8524
通讯作者	张涛
产权排序	待补充
合作状况	英
英文摘要	in this work, the hydroxyalkylation/alkylation of 2-methylfuran (2-mf) with acetone and butanal was investigated over a series of solid acid catalysts. among the investigated candidates, nafion-212 resin demonstrated the highest activity and stability for both reactions. butanal is more reactive than acetone in hydroxyalkylation/alkylation, which can be rationalized by the steric and electronic effects of alkyl group. finally, the hydroxyalkylation/alkylation products as prepared were directly hydrodeoxygenated over pd/c, pt/c and ni-wxc/c catalysts. evidently higher carbon yields to diesel were obtained when hydroxyalkylation/alkylation product of 2-mf with butanal was used as the feedstock. this can be considered as another advantage of 2-mf-butanal route. it is interesting that ni-wxc/c catalyst exhibited excellent catalytic performance and good stability in the hydrodeoxygenation of hydroxyalkylation/alkylation products, which made it a promising substitute for the noble metal catalysts. (c) 2013 elsevier ltd. all rights reserved.
学科主题	物理化学
WOS标题词	science & technology ; life sciences & biomedicine ; technology
类目[WOS]	agricultural engineering ; biotechnology & applied microbiology ; energy & fuels
研究领域[WOS]	agriculture ; biotechnology & applied microbiology ; energy & fuels
关键词[WOS]	high-quality diesel ; high-surface-area ; mesoporous carbon ; solid acid ; catalytic conversion ; carbide catalysts ; ethylene-glycol ; cellulose ; biomass ; hemicellulose
收录类别	SCI
资助信息	1，1
原文出处	72
语种	英语
WOS记录号	WOS:000328512800001
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119424]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
推荐引用方式 GB/T 7714	Li, Guangyi,Li, Ning,Yang, Jinfan,et al. Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose[J]. bioresource technology,2013,134:66-72.
APA	Li, Guangyi.,Li, Ning.,Yang, Jinfan.,Wang, Aiqin.,Wang, Xiaodong.,...&Zhang, Tao.(2013).Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose.bioresource technology,134,66-72.
MLA	Li, Guangyi,et al."Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose".bioresource technology 134(2013):66-72.