Sn doped ZnO layered porous nanocrystals with hierarchical structures and modified surfaces for gas sensors

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 研究所（批量导入）

	Sn doped ZnO layered porous nanocrystals with hierarchical structures and modified surfaces for gas sensors
	Yao, Mingshui 1,2; Ding, Fei 1; Cao, Yuebin 4; Hu, Peng 1; Fan, Junmei 1; Lu, Chen 1,2; Yuan, Fangli 1; Shi, Changyong 3; Chen, Yunfa 1
刊名	SENSORS AND ACTUATORS B-CHEMICAL
	2014-10-01
卷号	201 期号:1 页码:255-265
关键词	MOX sensors Hierarchical structure Modified surfaces Sn doping VOCs
ISSN号	0925-4005
其他题名	Sens. Actuator B-Chem.
中文摘要	In this paper, a simple solvothermal method is developed for the synthesis of Sn doped ZnO layered porous nanocrystal (Sn-ZLPC). Scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy are used to characterize the detailed structures and surface/near-surface chemical composition of the as-prepared products. Sn doping is found to be the key factor controlling the layered porous structure. The possible growth mechanism of Sn-ZLPC is also discussed. As the stability of target gas increases, the optimal operating temperature shifts from 300 degrees C to 500 degrees C and the highest response shifts to the sample with high atomic ratio of Sn. The later shift is attributed to the alternate key influence of the activation energy and adsorption/desorption of oxygen ions. 5.0 at% Sn-ZLPC exhibits the best sensing properties to VOCs due to the combined effect of low activation energy, adsorption/desorption of oxygen ions and the mesoporous hierarchical structure. (C) 2014 Elsevier B.V. All rights reserved.
英文摘要	In this paper, a simple solvothermal method is developed for the synthesis of Sn doped ZnO layered porous nanocrystal (Sn-ZLPC). Scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy are used to characterize the detailed structures and surface/near-surface chemical composition of the as-prepared products. Sn doping is found to be the key factor controlling the layered porous structure. The possible growth mechanism of Sn-ZLPC is also discussed. As the stability of target gas increases, the optimal operating temperature shifts from 300 degrees C to 500 degrees C and the highest response shifts to the sample with high atomic ratio of Sn. The later shift is attributed to the alternate key influence of the activation energy and adsorption/desorption of oxygen ions. 5.0 at% Sn-ZLPC exhibits the best sensing properties to VOCs due to the combined effect of low activation energy, adsorption/desorption of oxygen ions and the mesoporous hierarchical structure. (C) 2014 Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Analytical ; Electrochemistry ; Instruments & Instrumentation
研究领域[WOS]	Chemistry ; Electrochemistry ; Instruments & Instrumentation
关键词[WOS]	SENSING PROPERTIES ; THIN-FILMS ; HOLLOW SPHERES ; NANOPARTICLES ; TEMPERATURE ; NANOWIRES ; PROPERTY ; CONDUCTANCE ; SENSITIVITY ; PERFORMANCE
收录类别	SCI
原文出处	://WOS:000338705700037
语种	英语
WOS记录号	WOS:000338705700037
公开日期	2014-08-28
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/11015]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multi Phase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci UCAS, Beijing 100049, Peoples R China 3.Beijing Inst Fash Technol, Dept Elements, Beijing 100029, Peoples R China 4.Hanyang Univ, Dept Chem Engn, Ansan 426791, Kyeonggi Do, South Korea
推荐引用方式 GB/T 7714	Yao, Mingshui,Ding, Fei,Cao, Yuebin,et al. Sn doped ZnO layered porous nanocrystals with hierarchical structures and modified surfaces for gas sensors[J]. SENSORS AND ACTUATORS B-CHEMICAL,2014,201(1):255-265.
APA	Yao, Mingshui.,Ding, Fei.,Cao, Yuebin.,Hu, Peng.,Fan, Junmei.,...&Chen, Yunfa.(2014).Sn doped ZnO layered porous nanocrystals with hierarchical structures and modified surfaces for gas sensors.SENSORS AND ACTUATORS B-CHEMICAL,201(1),255-265.
MLA	Yao, Mingshui,et al."Sn doped ZnO layered porous nanocrystals with hierarchical structures and modified surfaces for gas sensors".SENSORS AND ACTUATORS B-CHEMICAL 201.1(2014):255-265.