An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A | |
Zhang, Xing ; Liu, Jun ; Sun, Xue ; Du, Yuguo | |
刊名 | TETRAHEDRON
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2013 | |
卷号 | 69期号:5页码:1553-1558 |
通讯作者 | Liu, J |
中文摘要 | Rapid and efficient reduction of allcyne bond in the presence of a vinyl iodide is established using freshly prepared Brown's P2-Ni as the catalyst, affording the semihydrogenated alkene products in good to excellent yields (73-91%). Based on this new method, a stereoselective synthesis of the key C22-C31 fragment of marine macrolide leiodolide A has been developed. (C) 2012 Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
WOS记录号 | WOS:000315064600018 |
公开日期 | 2014-06-06 |
内容类型 | 期刊论文 |
源URL | [http://ir.rcees.ac.cn/handle/311016/7530] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Zhang, Xing,Liu, Jun,Sun, Xue,et al. An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A[J]. TETRAHEDRON,2013,69(5):1553-1558. |
APA | Zhang, Xing,Liu, Jun,Sun, Xue,&Du, Yuguo.(2013).An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A.TETRAHEDRON,69(5),1553-1558. |
MLA | Zhang, Xing,et al."An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A".TETRAHEDRON 69.5(2013):1553-1558. |
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