An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 环境化学与生态毒理学国家重点实验室

	An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A
	Zhang, Xing ; Liu, Jun ; Sun, Xue ; Du, Yuguo
刊名	TETRAHEDRON
	2013
卷号	69 期号:5 页码:1553-1558
通讯作者	Liu, J
中文摘要	Rapid and efficient reduction of allcyne bond in the presence of a vinyl iodide is established using freshly prepared Brown's P2-Ni as the catalyst, affording the semihydrogenated alkene products in good to excellent yields (73-91%). Based on this new method, a stereoselective synthesis of the key C22-C31 fragment of marine macrolide leiodolide A has been developed. (C) 2012 Elsevier Ltd. All rights reserved.
收录类别	SCI
WOS记录号	WOS:000315064600018
公开日期	2014-06-06
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/7530]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Zhang, Xing,Liu, Jun,Sun, Xue,et al. An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A[J]. TETRAHEDRON,2013,69(5):1553-1558.
APA	Zhang, Xing,Liu, Jun,Sun, Xue,&Du, Yuguo.(2013).An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A.TETRAHEDRON,69(5),1553-1558.
MLA	Zhang, Xing,et al."An efficient cis-reduction of alkyne to alkene in the presence of a vinyl iodide: stereoselective synthesis of the C22-C31 fragment of leiodolide A".TETRAHEDRON 69.5(2013):1553-1558.