Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids

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	Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids
	Chen, Shimou 1; Zhang, Suojiang 1; Liu, Xiaomin 1; Wang, Jinquan 1; Wang, Jianji 2; Dong, Kun 1; Sun, Jian 1; Xu, Baohua 1
刊名	PHYSICAL CHEMISTRY CHEMICAL PHYSICS
	2014
卷号	16 期号:13 页码:5893-5906
关键词	ray photoelectron-spectroscopy molecular-dynamics simulations silica-derived networks alkyl chain-length room-temperature aqueous-solution micelle formation aggregation behavior nanostructural organization physicochemical properties
ISSN号	1463-9076
其他题名	Phys. Chem. Chem. Phys.
中文摘要	The microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in physiochemical properties and behavior of ILs. The existence of clusters (or microheterogeneous structure) is one of the main features for many ILs, which provides fundamental information for understanding the performance of ILs in their applications. This perspective concentrates on the recent progresses in IL clusters research. Firstly, we give a brief introduction on the structure of clusters in neat ILs and IL solutions. Secondly, the possible formation mechanism of the IL clusters is described. Then, the effects of the clusters on the physicochemical properties, interfacial properties, confined geometry and assembly processes of ILs are discussed. Finally, we address the associated challenges and prospects on the future study of IL clusters.
英文摘要	The microstructure of ionic liquids (ILs) has attracted much attention due to their relevance in physiochemical properties and behavior of ILs. The existence of clusters (or microheterogeneous structure) is one of the main features for many ILs, which provides fundamental information for understanding the performance of ILs in their applications. This perspective concentrates on the recent progresses in IL clusters research. Firstly, we give a brief introduction on the structure of clusters in neat ILs and IL solutions. Secondly, the possible formation mechanism of the IL clusters is described. Then, the effects of the clusters on the physicochemical properties, interfacial properties, confined geometry and assembly processes of ILs are discussed. Finally, we address the associated challenges and prospects on the future study of IL clusters.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]	Chemistry ; Physics
关键词[WOS]	RAY PHOTOELECTRON-SPECTROSCOPY ; MOLECULAR-DYNAMICS SIMULATIONS ; SILICA-DERIVED NETWORKS ; ALKYL CHAIN-LENGTH ; ROOM-TEMPERATURE ; AQUEOUS-SOLUTION ; MICELLE FORMATION ; AGGREGATION BEHAVIOR ; NANOSTRUCTURAL ORGANIZATION ; PHYSICOCHEMICAL PROPERTIES
收录类别	SCI
原文出处	://WOS:000332474700001
语种	英语
WOS记录号	WOS:000332474700001
公开日期	2014-05-06
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/8132]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 2.Henan Normal Univ, Minist Educ, Key Lab Green Chem Media & React, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
推荐引用方式 GB/T 7714	Chen, Shimou,Zhang, Suojiang,Liu, Xiaomin,et al. Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2014,16(13):5893-5906.
APA	Chen, Shimou.,Zhang, Suojiang.,Liu, Xiaomin.,Wang, Jinquan.,Wang, Jianji.,...&Xu, Baohua.(2014).Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,16(13),5893-5906.
MLA	Chen, Shimou,et al."Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 16.13(2014):5893-5906.