Reduction of citral in water under typical transfer hydrogenation conditions-Reaction mechanisms with evolution of and hydrogenation by molecular hydrogen

	Reduction of citral in water under typical transfer hydrogenation conditions-Reaction mechanisms with evolution of and hydrogenation by molecular hydrogen
	Liu RX ; Wang Y ; Cheng HY ; Yu YC ; Zhao FY ; Arai M
刊名	journal of molecular catalysis a-chemical
	2013
卷号	366 页码:315-320
关键词	CATALYTIC TRANSFER HYDROGENATION ALPHA ASYMMETRIC TRANSFER HYDROGENATION FORMIC-ACID DECOMPOSITION HYDRATED NICKEL CHLORIDE SELECTIVE HYDROGENATION FORMATE SALTS NANOPARTICLES PD/C GENERATION BETA-UNSATURATED CARBONYL-COMPOUNDS
ISSN号	1381-1169
通讯作者	zhao fy
中文摘要	the reduction of an alpha,beta-unsaturated aldehyde, citral, was investigated over a 10 wt% pd catalyst under transfer hydrogenation (th) conditions in a closed system with microwave assistance. surprisingly, it was found that hydrogen was produced quite fast under the microwave irradiation during the reaction, and the reduction of citral was proved to go mainly through consecutive pathways of hydrogen production - hydrogenation rather than those commonly considered for th reactions. similar reaction pathways were also observed with a homogeneous catalyst of [rucl2(c6h6)](2) and other typical hydrogen donors like formate salts and isopropanol, which are usually used in the typical transfer hydrogenations. (c) 2012 elsevier b.v. all rights reserved.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000313230200041
公开日期	2014-04-18
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50409]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Liu RX,Wang Y,Cheng HY,et al. Reduction of citral in water under typical transfer hydrogenation conditions-Reaction mechanisms with evolution of and hydrogenation by molecular hydrogen[J]. journal of molecular catalysis a-chemical,2013,366:315-320.
APA	Liu RX,Wang Y,Cheng HY,Yu YC,Zhao FY,&Arai M.(2013).Reduction of citral in water under typical transfer hydrogenation conditions-Reaction mechanisms with evolution of and hydrogenation by molecular hydrogen.journal of molecular catalysis a-chemical,366,315-320.
MLA	Liu RX,et al."Reduction of citral in water under typical transfer hydrogenation conditions-Reaction mechanisms with evolution of and hydrogenation by molecular hydrogen".journal of molecular catalysis a-chemical 366(2013):315-320.