Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system

	Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system
	Parveen S ; Zhang W ; Yuan YL ; Hu LZ ; Gilani MRHS ; Rehman AU ; Xu GB
刊名	journal of electroanalytical chemistry
	2013
卷号	688 页码:45-48
关键词	TRIS(2 ELECTROCHEMILUMINESCENCE COMPLEXES 2'-BIPYRIDYL)RUTHENIUM(II)
ISSN号	1572-6657
通讯作者	rehman au
中文摘要	2-(dibutylamino)ethanol (dbae) is a highly effective coreactant for ru(bpy)(3)(2-) electrochemiluminescence (ecl) and ru(phen)(3)(2+) is a well-known ecl luminophore. in this study, ecl of ru(phen)(3)(2+)/dbae has been investigated for the first time. this study has been carried out using cyclic voltametry and amperometry. the results imply that amperometry is found to be superior to cyclic voltametry as it shows approximately five fold enhancement in ecl emission intensity. furthermore, compared to ru(bpy)(3)(2+), ru(phen)(3)(2+) provides several fold increase in ecl intensities with dbae. sensitive detection of ru(phen)(3)(2+) is achieved with a linear range over approximately four orders of magnitude using very low concentration of dbae (5 mm). (c) 2012 elsevier b.v. all rights reserved.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000317158800009
公开日期	2014-04-18
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50311]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Parveen S,Zhang W,Yuan YL,et al. Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system[J]. journal of electroanalytical chemistry,2013,688:45-48.
APA	Parveen S.,Zhang W.,Yuan YL.,Hu LZ.,Gilani MRHS.,...&Xu GB.(2013).Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system.journal of electroanalytical chemistry,688,45-48.
MLA	Parveen S,et al."Electrogenerated chemiluminescence of Ru(phen)(3)(2+)/2-(dibutylamino)ethanol system".journal of electroanalytical chemistry 688(2013):45-48.