Novel Vanadium(III) Complexes with Tridentate Phenoxy-Phosphine [O,P(=O),O] Ligands: Synthesis, Characterization, and Catalytic Behavior of Ethylene Polymerization and Copolymerization with 10-Undecen-1-ol

	Novel Vanadium(III) Complexes with Tridentate Phenoxy-Phosphine [O,P(=O),O] Ligands: Synthesis, Characterization, and Catalytic Behavior of Ethylene Polymerization and Copolymerization with 10-Undecen-1-ol
	Zhang SW ; Zhang GB ; Lu LP ; Li YS
刊名	journal of polymer science part a-polymer chemistry
	2013
卷号	51 期号:4 页码:844-854
关键词	TRANSFER RADICAL POLYMERIZATION TRANSITION-METAL-COMPLEXES OLEFIN POLYMERIZATION TITANIUM COMPLEXES ALPHA-OLEFINS STRUCTURAL-CHARACTERIZATION GRAFT-COPOLYMERS ZIEGLER-NATTA METALLOCENE/METHYLALUMINOXANE CATALYST LINEAR POLYETHYLENE
ISSN号	0887-624x
通讯作者	li ys
中文摘要	a series of novel vanadium(iii) complexes bearing tridentate phenoxy-phosphine [o,p,o] ligands and phosphine oxide-bridged bisphenolato [o, p o, o] ligands, which differ in the steric and electronic properties, have been synthesized and characterized. these complexes were characterized by fourier transform infrared spectroscopy (ftir) and mass spectra as well as elemental analysis. single-crystal x-ray diffraction revealed that complexes 3c and 4e adopt an octahedral geometry around the vanadium center. in the presence of et2alcl as a cocatalyst, these complexes displayed high catalytic activities up to 22.8 kg pe/mmol(v).h.bar for ethylene polymerization, and produced high-molecular-weight polymers. introducing additional oxygen atom on phosphorus atom of [o, p, o] ligands has resulted in significant changes on the aspect of steric/electronic effect, which has an impact on polymerization performance. 3c and 4c/et2alcl catalytic systems were tolerant to elevated temperature (70 degrees c) and yielded unimodal polyethylenes, indicating the single-site behavior of these catalysts. by pretreating with equimolar amounts of alkylaluminums, functional alpha-olefin 10-undecen-1-ol can be efficiently incorporated into polyethylene chains. 10-undecen-1-ol incorporation can easily reach 14.6 mol % under the mild conditions. other reaction parameters that influenced the polymerization behavior, such as reaction temperature, al/v (molar ratio), and comonomer concentration, are also examined in detail. (c) 2012 wiley periodicals, inc. j. polym. sci., part a: polym. chem. 2013, 51, 844-854
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000314150500011
公开日期	2014-04-16
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/50039]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zhang SW,Zhang GB,Lu LP,et al. Novel Vanadium(III) Complexes with Tridentate Phenoxy-Phosphine [O,P(=O),O] Ligands: Synthesis, Characterization, and Catalytic Behavior of Ethylene Polymerization and Copolymerization with 10-Undecen-1-ol[J]. journal of polymer science part a-polymer chemistry,2013,51(4):844-854.
APA	Zhang SW,Zhang GB,Lu LP,&Li YS.(2013).Novel Vanadium(III) Complexes with Tridentate Phenoxy-Phosphine [O,P(=O),O] Ligands: Synthesis, Characterization, and Catalytic Behavior of Ethylene Polymerization and Copolymerization with 10-Undecen-1-ol.journal of polymer science part a-polymer chemistry,51(4),844-854.
MLA	Zhang SW,et al."Novel Vanadium(III) Complexes with Tridentate Phenoxy-Phosphine [O,P(=O),O] Ligands: Synthesis, Characterization, and Catalytic Behavior of Ethylene Polymerization and Copolymerization with 10-Undecen-1-ol".journal of polymer science part a-polymer chemistry 51.4(2013):844-854.