Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology
Hao ZM ; Song SY ; Su SQ ; Song XZ ; Zhu M ; Zhao SN ; Meng X ; Zhang HJ
刊名crystal growth & design
2013
卷号13期号:3页码:976-980
关键词METAL-ORGANIC FRAMEWORKS 3 IMIDAZOLE GROUPS SPONTANEOUS RESOLUTION MICROPOROUS FRAMEWORK COBALT(III) COMPLEXES ACHIRAL PRECURSORS SELF-ORGANIZATION CARBON NANOTUBES ASSEMBLIES LIGAND
ISSN号1528-7483
通讯作者zhang hj
中文摘要this article reports a pair of novel chiral sandwichlike complexes for the first time. in the two complexes, lanthanide eu3+ ions and na+ ions are sandwiched between schiff base ligands, resulting in a two-dimensional plane. for both of the complexes, the intraplane and interplane interactions are utterly different. the adjacent planes are held together by weak van der waals forces, while the single plane is formed by covalently bonded intraplane n-eu-o, o-eu-o, and o-na-o atoms. on the basis of this characteristic information derived from their molecular building blocks, we studied three-dimensional morphology which has good agreement with expected lamellar morphology. furthermore, to examine the chiroptical and stable activities, the cd spectra were investigated in the solution of methanol and five different solid forms.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000315936800003
公开日期2014-04-16
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/50001]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Hao ZM,Song SY,Su SQ,et al. Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology[J]. crystal growth & design,2013,13(3):976-980.
APA Hao ZM.,Song SY.,Su SQ.,Song XZ.,Zhu M.,...&Zhang HJ.(2013).Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology.crystal growth & design,13(3),976-980.
MLA Hao ZM,et al."Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology".crystal growth & design 13.3(2013):976-980.
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