Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology | |
Hao ZM ; Song SY ; Su SQ ; Song XZ ; Zhu M ; Zhao SN ; Meng X ; Zhang HJ | |
刊名 | crystal growth & design
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2013 | |
卷号 | 13期号:3页码:976-980 |
关键词 | METAL-ORGANIC FRAMEWORKS 3 IMIDAZOLE GROUPS SPONTANEOUS RESOLUTION MICROPOROUS FRAMEWORK COBALT(III) COMPLEXES ACHIRAL PRECURSORS SELF-ORGANIZATION CARBON NANOTUBES ASSEMBLIES LIGAND |
ISSN号 | 1528-7483 |
通讯作者 | zhang hj |
中文摘要 | this article reports a pair of novel chiral sandwichlike complexes for the first time. in the two complexes, lanthanide eu3+ ions and na+ ions are sandwiched between schiff base ligands, resulting in a two-dimensional plane. for both of the complexes, the intraplane and interplane interactions are utterly different. the adjacent planes are held together by weak van der waals forces, while the single plane is formed by covalently bonded intraplane n-eu-o, o-eu-o, and o-na-o atoms. on the basis of this characteristic information derived from their molecular building blocks, we studied three-dimensional morphology which has good agreement with expected lamellar morphology. furthermore, to examine the chiroptical and stable activities, the cd spectra were investigated in the solution of methanol and five different solid forms. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000315936800003 |
公开日期 | 2014-04-16 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/50001] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Hao ZM,Song SY,Su SQ,et al. Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology[J]. crystal growth & design,2013,13(3):976-980. |
APA | Hao ZM.,Song SY.,Su SQ.,Song XZ.,Zhu M.,...&Zhang HJ.(2013).Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology.crystal growth & design,13(3),976-980. |
MLA | Hao ZM,et al."Design and Synthesis of Enantiomerically Pure Chiral Sandwichlike Lamellar Structure: New Explorations from Molecular Building Blocks to Three-Dimensional Morphology".crystal growth & design 13.3(2013):976-980. |
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