Luminescence and Energy Transfer Properties of Ca2Ba3(PO4)(3)Cl and Ca2Ba3(PO4)(3)Cl:A (A = Eu2+/Ce3+/Dy3+/Tb3+) under UV and Low-Voltage Electron Beam Excitation

	Luminescence and Energy Transfer Properties of Ca2Ba3(PO4)(3)Cl and Ca2Ba3(PO4)(3)Cl:A (A = Eu2+/Ce3+/Dy3+/Tb3+) under UV and Low-Voltage Electron Beam Excitation
	Shang MM ; Geng DL ; Yang DM ; Kang XJ ; Zhang Y ; Lin J
刊名	inorganic chemistry
	2013
卷号	52 期号:6 页码:3102-3112
关键词	LIGHT-EMITTING-DIODES OPTICAL-PROPERTIES FLUORESCENT LAMP PHOSPHOR LEDS EMISSION TB NANOPARTICLES COLOR CE3+
ISSN号	0020-1669
通讯作者	lin j
中文摘要	pure ca2ba3(po4)(3)cl and rare earth ion (eu2+/ce3+/dy3+/tb3+) doped ca2ba3(po4)(3)cl phosphors with the apatite structure have been prepared via a pechini-type sol gel process. x-ray diffraction (xrd) and structure refinement, photoluminescence (pl) spectra, cathodoluminescence (cl) spectra, absolute quantum yield, as well as lifetimes were utilized to characterize samples. under uv light excitation, the undoped ca2ba3(po4)(3)cl sample shows broad band photoluminescence centered near 480 nm after being reduced due to the defect structure. eu2+ and ce3+ ion doped ca2ba3(po4)(3)cl samples also show broad 5d -> 4f transitions with cyan and blue colors and higher quantum yields (72% for ca2ba3(po4)(3)cl:0.04eu(2+); 67% for ca2ba3(po4)(3)cl:0.016ce(3+)) for dy3+ and tb3+ doped ca2ba3(po4)(3)cl samples, they give strong line emissions coming from 41 4f transitions. moreover, the ce3+ ion can transfer its energy to the tb3+ ion in the ca2ba3(po4)(3)cl host, and the energy transfer mechanism has been demonstrated to be a resonant type, via a dipole-quadrupole interaction. however, under the low voltage electron beam excitation, tb3+ ion doped ca2ba3(po4)(3)cl samples present different luminescence properties compared with their pl spectra, which is ascribed to the different excitation mechanism. on the basis of the good pl and cl properties of the ca2ba3(po4)(3)cl:a (a = ce3+/eu2+/tb3+/dy3+), ca2ba3(po4)(3)cl might be promising for application in solid state lighting and field-emission displays.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000316439400039
公开日期	2014-04-16
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/49971]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Shang MM,Geng DL,Yang DM,et al. Luminescence and Energy Transfer Properties of Ca2Ba3(PO4)(3)Cl and Ca2Ba3(PO4)(3)Cl:A (A = Eu2+/Ce3+/Dy3+/Tb3+) under UV and Low-Voltage Electron Beam Excitation[J]. inorganic chemistry,2013,52(6):3102-3112.
APA	Shang MM,Geng DL,Yang DM,Kang XJ,Zhang Y,&Lin J.(2013).Luminescence and Energy Transfer Properties of Ca2Ba3(PO4)(3)Cl and Ca2Ba3(PO4)(3)Cl:A (A = Eu2+/Ce3+/Dy3+/Tb3+) under UV and Low-Voltage Electron Beam Excitation.inorganic chemistry,52(6),3102-3112.
MLA	Shang MM,et al."Luminescence and Energy Transfer Properties of Ca2Ba3(PO4)(3)Cl and Ca2Ba3(PO4)(3)Cl:A (A = Eu2+/Ce3+/Dy3+/Tb3+) under UV and Low-Voltage Electron Beam Excitation".inorganic chemistry 52.6(2013):3102-3112.