Zirconium Phosphate-Methylene Blue Composite Immobilized at Room-Temperature Ionic Liquid Matrix for Electrochemical Detection of NADH. | |
Xiaoying Zeng ; Juxing Jiang ; Haiyun Zhang ; Wenjing Lu ; Dawei Pan* | |
刊名 | JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN
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2013 | |
卷号 | 35期号:2页码:272-275 |
关键词 | CARBON NANOTUBES ELECTRODE ADSORPTION FILMS |
通讯作者 | Pan, DW (reprint author), Chinese Acad Sci, YIC, Key Lab Coastal Zone Environm Processes & Ecol Re, Yantai 264003, Shandong, Peoples R China. dwpan@yic.ac.cn |
中文摘要 | Electroactive methylene blue (MB) entrapped in alpha-zirconium phosphate (ZrP) were first synthesized by a simple chemical method. Room-temperature ionic liquid (IL) was used as a matrix to immobilize ZrP-MB composite on pyrolytic graphite (PG) electrode and the resulting modified electrode can be utilized in electrocatalytic oxidation of NADH. Because of the combination of the excellent electroactivity of MB, the good chemical and mechanical properties of ZrP and the good ionic conductivity of IL, the response current of NADH at PG/ZrP-MB/IL electrode is much larger than that in bare and ZrP-IL electrode and the interference of ascorbic acid can be avoided efficiently. The PG/ZrP-MB/IL electrode displayed high sensitivity (76.5 mA M-1 cm(-2)), low detection limit (6 mu M), fast response time (within 5s) and wide linear range (6-540 mu M). |
学科主题 | Chemistry; Multidisciplinary |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China [21007087]; Chinese Academy of Sciences [KZCX2-YW-JS208]; Natural Science Foundation of Shandong Province [BS2010HZ030]; Youth Innovation Promotion Association of CAS |
语种 | 英语 |
公开日期 | 2014-04-22 |
内容类型 | 期刊论文 |
源URL | [http://ir.yic.ac.cn/handle/133337/6792] ![]() |
专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
推荐引用方式 GB/T 7714 | Xiaoying Zeng,Juxing Jiang,Haiyun Zhang,et al. Zirconium Phosphate-Methylene Blue Composite Immobilized at Room-Temperature Ionic Liquid Matrix for Electrochemical Detection of NADH.[J]. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN,2013,35(2):272-275. |
APA | Xiaoying Zeng,Juxing Jiang,Haiyun Zhang,Wenjing Lu,&Dawei Pan*.(2013).Zirconium Phosphate-Methylene Blue Composite Immobilized at Room-Temperature Ionic Liquid Matrix for Electrochemical Detection of NADH..JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN,35(2),272-275. |
MLA | Xiaoying Zeng,et al."Zirconium Phosphate-Methylene Blue Composite Immobilized at Room-Temperature Ionic Liquid Matrix for Electrochemical Detection of NADH.".JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN 35.2(2013):272-275. |
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