Striking Influence about HZSM-5 Content and Nickel Catalyst on Catalytic Carbonization of Polypropylene and Polyethylene into Carbon Nanomaterials

	Striking Influence about HZSM-5 Content and Nickel Catalyst on Catalytic Carbonization of Polypropylene and Polyethylene into Carbon Nanomaterials
	Gong J ; Feng JD ; Liu J ; Muhammad R ; Chen XC ; Jiang ZW ; Mijowska E ; Wen X ; Tang T
刊名	industrial & engineering chemistry research
	2013
卷号	52 期号:44 页码:15578-15588
关键词	WASTE PLASTICS NANOTUBES PYROLYSIS COMBUSTION CONVERSION POLYSTYRENE COMPOSITES REDUCTION MECHANISM NETWORKS
ISSN号	0888-5885
通讯作者	chen xc
中文摘要	a one-pot approach was established to effectively convert polypropylene (pp) and linear low density polyethylene (lldpe) into carbon nanomaterials (cnms) including cup-stacked carbon nanotubes and carbon nanofibers under the combined catalysis of hzsm-5/nio or hzsm-5/ni2o3 at 700 degrees c. the effects of hzsm-5 content, a nickel catalyst, and the carbon precursor on the morphology, microstructure, phase structure, and thermal stability of cnms were investigated with scanning electron microscopy, transmission electron microscopy (tem), high-resolution tem, x-ray diffraction, raman spectroscopy, and thermal gravimetric analysis. the effect of hzsm-5 content on the degradation products of pp and lldpe was analyzed by gas chromatography and gas chromatography mass spectrometry. with increasing hzsm-5 content, the yields of light hydrocarbons and aromatics increased due to proton acid sites on the surface of hzsm-5 catalyzing cracking of pp or lldpe degradation products. this one-pot approach provides a novel potential way to largely transform mixed waste polyolefin into high value-added cnms.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000326774700041
公开日期	2014-04-15
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/49486]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Gong J,Feng JD,Liu J,et al. Striking Influence about HZSM-5 Content and Nickel Catalyst on Catalytic Carbonization of Polypropylene and Polyethylene into Carbon Nanomaterials[J]. industrial & engineering chemistry research,2013,52(44):15578-15588.
APA	Gong J.,Feng JD.,Liu J.,Muhammad R.,Chen XC.,...&Tang T.(2013).Striking Influence about HZSM-5 Content and Nickel Catalyst on Catalytic Carbonization of Polypropylene and Polyethylene into Carbon Nanomaterials.industrial & engineering chemistry research,52(44),15578-15588.
MLA	Gong J,et al."Striking Influence about HZSM-5 Content and Nickel Catalyst on Catalytic Carbonization of Polypropylene and Polyethylene into Carbon Nanomaterials".industrial & engineering chemistry research 52.44(2013):15578-15588.