Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries | |
Wang, Xuejiang; Liu, Zhihong; Zhang, Chuanjian; Kong, Qingshan; Yao, Jianhua; Han, Pengxian; Jiang, Wen; Xu, Hongxia; Cui, Guanglei | |
刊名 | ELECTROCHIMICA ACTA |
2013-03-01 | |
卷号 | 92期号:92页码:132-138 |
关键词 | Polymer electrolytes Lithium salts High temperature Lithium ion batteries |
英文摘要 | A novel polymeric lithium tartaric acid borate (PLTB) was synthesized via an one-step reaction in aqueous solution. The polymer electrolyte of PLTB@PVDF-HFP (poly(vinylidene fluoride-co-hexafluoropropene)) was developed by a doctor-blading followed by a soaking process in propylene carbonate (PC). It was manifested that the PC swollen PLTB@PVDF-HFP exhibited excellent electrochemical stability and compatibility with lithium metal electrode, high ionic conductivity and high lithium ion transference number at an operating temperature of 80 degrees C. The cells using the PC swollen PLTB@PVDF-HFP as electrolyte showed stable charge/discharge profiles, preferable rate capability and satisfactory cycling performance at high temperature. These superior performances of PC swollen PLTB@PVDF-HFP could endow this class of polymer electrolyte a very promising application in lithium batteries operating at relatively high temperature. (C) 2013 Elsevier Ltd. All rights reserved. |
学科主题 | 仿生能源系统 |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Electrochemistry |
研究领域[WOS] | Electrochemistry |
关键词[WOS] | POLYANIONIC SOLID ELECTROLYTES ; WEAK COULOMB TRAPS ; ION BATTERIES ; NONAQUEOUS SOLUTIONS ; SALTS ; PERFORMANCE ; ANODE ; CONDUCTIVITY ; STABILITY ; COMPLEXES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000316520100017 |
公开日期 | 2014-03-21 |
内容类型 | 期刊论文 |
源URL | [http://ir.qibebt.ac.cn:8080/handle/337004/1604] |
专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Xuejiang,Liu, Zhihong,Zhang, Chuanjian,et al. Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries[J]. ELECTROCHIMICA ACTA,2013,92(92):132-138. |
APA | Wang, Xuejiang.,Liu, Zhihong.,Zhang, Chuanjian.,Kong, Qingshan.,Yao, Jianhua.,...&Cui, Guanglei.(2013).Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries.ELECTROCHIMICA ACTA,92(92),132-138. |
MLA | Wang, Xuejiang,et al."Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries".ELECTROCHIMICA ACTA 92.92(2013):132-138. |
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