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Solvent-Assisted Interfacial Tension Deformation of Spherical Particles for the Fabrication of Non-Spherical Particle Arrays
Zheng, L ; Ma, ZH ; Geng, C ; Yan, QF
刊名PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION
2013
卷号30期号:9页码:812
关键词interfacial tension non-spherical particle arrays solvent annealing
ISSN号0934-0866
通讯作者Zheng, L (reprint author), Tsinghua Univ, Dept Chem, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China.
中文摘要A facile and efficient approach is developed for the fabrication of asymmetric non-spherical polymer particle arrays. A specific amount of solvent is provided to interact with the spherical polymer particles to intensify the segmental mobility, thus suppressing the viscosity and the glass transition temperature of the polymer particles. The spherical polymer particlesin therubbery state are deformed into non-spherical particle arrays at the gas/liquid interface. The upper parts of the polymer particles that protrude out of the liquid phase undergo deformation by interfacial tensions at the three-phase contact line, allowing the formation of a ridge of polymer with a protrusion on the top surface. Simultaneously, the lower parts of the polymer particles submerged under the liquid phase are subjected to enormous surface tension at the contact points, leading to a non-linear coalescence behavior of the neighboring polymer particles.
资助信息National Key Basic Research Program of China [2013CB632902]; Natural Science Foundation of China [50903046, 51132005, 51173097]; Tsinghua University Initiative Scientific Research Program; Tsinghua National Laboratory for Information Science and Technology (TNList) Cross-discipline Foundation
语种英语
公开日期2014-01-17
内容类型期刊论文
源URL[http://ir.iphy.ac.cn/handle/311004/57451]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Zheng, L,Ma, ZH,Geng, C,et al. Solvent-Assisted Interfacial Tension Deformation of Spherical Particles for the Fabrication of Non-Spherical Particle Arrays[J]. PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION,2013,30(9):812.
APA Zheng, L,Ma, ZH,Geng, C,&Yan, QF.(2013).Solvent-Assisted Interfacial Tension Deformation of Spherical Particles for the Fabrication of Non-Spherical Particle Arrays.PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION,30(9),812.
MLA Zheng, L,et al."Solvent-Assisted Interfacial Tension Deformation of Spherical Particles for the Fabrication of Non-Spherical Particle Arrays".PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION 30.9(2013):812.
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