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In-Situ Raman Spectra of Single-Walled Carbon Nanotube/Epoxy Nanocomposite Film Under Strain
Li, JZ ; Niu, ZQ ; Zeng, QS ; Cai, L ; Zhang, XX ; Dong, HB ; Zhao, D ; Zhou, WY ; Xie, SS
刊名JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
2013
卷号13期号:2页码:1145
关键词Raman Spectra Carbon Nanotube Nanocomposite Film Strain Load Transfer Efficiency
ISSN号1533-4880
通讯作者Xie, SS (reprint author), Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China.
中文摘要In-situ Raman spectra under continuous strain have been carried out to follow the load transfer efficiency in a single-walled carbon nanotube/epoxy nanocomposite film, which was fabricated by a facile and filter-free infiltration method using directly synthesized SWNT film as skeleton. It was found that in the low elastic range of 1%, with the increase of applied strain, the G(-) and G(+) Raman bands downshift nearly lineally with corresponding ultrahigh rates up to -12 and -17 cm(-1)/% strain, respectively. As the applied strain decrease, these Raman bands upshift to their original frequencies with almost the same rates. These precise relationships between the Raman band shift and the applied strain enable this nanocomposite film promising stress or stain sensors. Furthermore, some Raman radial breathing modes (RBMs) disappear (appear) under larger strain (1.6%) and recover (vanish) when the strain is released, also verify the effective deformation of micro SWNTs induced by extra macro strain applied on the nanocomposite film. More interestingly, these frequency shifts and intensity vibrations are recoverable and repeatable, indicating the high elasticity of deformation in this strain region of 2%.
资助信息National Basic Research Program of China [2012CB932302]; National Natural Science foundation of China [90921012, 51172271]; Beijing Municipal Education Commission [YB20108000101]; Key Item of Knowledge Innovation Project of Chinese Academy of Sciences [KJCX2-YW-M01]
语种英语
公开日期2014-01-16
内容类型期刊论文
源URL[http://ir.iphy.ac.cn/handle/311004/57122]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Li, JZ,Niu, ZQ,Zeng, QS,et al. In-Situ Raman Spectra of Single-Walled Carbon Nanotube/Epoxy Nanocomposite Film Under Strain[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2013,13(2):1145.
APA Li, JZ.,Niu, ZQ.,Zeng, QS.,Cai, L.,Zhang, XX.,...&Xie, SS.(2013).In-Situ Raman Spectra of Single-Walled Carbon Nanotube/Epoxy Nanocomposite Film Under Strain.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,13(2),1145.
MLA Li, JZ,et al."In-Situ Raman Spectra of Single-Walled Carbon Nanotube/Epoxy Nanocomposite Film Under Strain".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 13.2(2013):1145.
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