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Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence
Zhang, XX ; Liu, DF ; Zhang, LH ; Li, WL ; Gao, M ; Ma, WJ ; Ren, Y ; Zeng, QS ; Niu, ZQ ; Zhou, WY ; Xie, SS
刊名JOURNAL OF MATERIALS CHEMISTRY
2009
卷号19期号:7页码:962
关键词OPTICAL-PROPERTIES PATTERNED GROWTH ZINC-OXIDE NANOWIRE NANOPARTICLES LIGHT
ISSN号0959-9428
通讯作者Xie, SS (reprint author), Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China.
中文摘要We demonstrate a promising route to fabricate large scale hexagonally patterned, vertically aligned ZnO nanorod arrays with small diameter. By adding 3-mercaptopropyltriethoxysilane (MPTES) molecules as a connection between catalyst and substrate the large size dispersion resulting from the removal of catalyst pattern is avoided, thus the catalyst particle pattern with tiny size dispersion and regular shape is obtained; the size can be tuned in a large range from 50 nm to 300 nm. Using this technique, ZnO nanorod arrays with tunable spacings and diameters are achieved, which also have uniform shape and length, good crystal quality, and vertical alignment on the substrate. Moreover, a pronounced blue-shift of ultraviolet (UV) luminescence spectra of ZnO nanorods with their diameters decreasing is observed. Combining the temperature-dependent photoluminescence (PL), we suggest that a materially decreased exciton-phonon interaction with the reduced diameter of ZnO nanorods is the main reason for the blue-shift of UV luminescence.
收录类别SCI
资助信息National Natural Science Foundation of China [90406022, 50702002]
语种英语
公开日期2013-09-24
内容类型期刊论文
源URL[http://ir.iphy.ac.cn/handle/311004/54443]  
专题物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式
GB/T 7714
Zhang, XX,Liu, DF,Zhang, LH,et al. Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence[J]. JOURNAL OF MATERIALS CHEMISTRY,2009,19(7):962.
APA Zhang, XX.,Liu, DF.,Zhang, LH.,Li, WL.,Gao, M.,...&Xie, SS.(2009).Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence.JOURNAL OF MATERIALS CHEMISTRY,19(7),962.
MLA Zhang, XX,et al."Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence".JOURNAL OF MATERIALS CHEMISTRY 19.7(2009):962.
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