Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence | |
Zhang, XX ; Liu, DF ; Zhang, LH ; Li, WL ; Gao, M ; Ma, WJ ; Ren, Y ; Zeng, QS ; Niu, ZQ ; Zhou, WY ; Xie, SS | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY
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2009 | |
卷号 | 19期号:7页码:962 |
关键词 | OPTICAL-PROPERTIES PATTERNED GROWTH ZINC-OXIDE NANOWIRE NANOPARTICLES LIGHT |
ISSN号 | 0959-9428 |
通讯作者 | Xie, SS (reprint author), Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China. |
中文摘要 | We demonstrate a promising route to fabricate large scale hexagonally patterned, vertically aligned ZnO nanorod arrays with small diameter. By adding 3-mercaptopropyltriethoxysilane (MPTES) molecules as a connection between catalyst and substrate the large size dispersion resulting from the removal of catalyst pattern is avoided, thus the catalyst particle pattern with tiny size dispersion and regular shape is obtained; the size can be tuned in a large range from 50 nm to 300 nm. Using this technique, ZnO nanorod arrays with tunable spacings and diameters are achieved, which also have uniform shape and length, good crystal quality, and vertical alignment on the substrate. Moreover, a pronounced blue-shift of ultraviolet (UV) luminescence spectra of ZnO nanorods with their diameters decreasing is observed. Combining the temperature-dependent photoluminescence (PL), we suggest that a materially decreased exciton-phonon interaction with the reduced diameter of ZnO nanorods is the main reason for the blue-shift of UV luminescence. |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China [90406022, 50702002] |
语种 | 英语 |
公开日期 | 2013-09-24 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/54443] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang, XX,Liu, DF,Zhang, LH,et al. Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence[J]. JOURNAL OF MATERIALS CHEMISTRY,2009,19(7):962. |
APA | Zhang, XX.,Liu, DF.,Zhang, LH.,Li, WL.,Gao, M.,...&Xie, SS.(2009).Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence.JOURNAL OF MATERIALS CHEMISTRY,19(7),962. |
MLA | Zhang, XX,et al."Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence".JOURNAL OF MATERIALS CHEMISTRY 19.7(2009):962. |
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