Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)

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	Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)
	Zhao, YN ; Ju, J ; Chen, XM ; Li, XH ; Wang, RJ ; Mai, ZH
刊名	JOURNAL OF SOLID STATE CHEMISTRY
	2002
卷号	165 期号:1 页码:182
关键词	LAYERED ZINC PHOSPHATE HYDROTHERMAL SYNTHESIS METAL PHOSPHATES TETRAHEDRA
ISSN号	0022-4596
通讯作者	Zhao, YN (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China.
中文摘要	A new zincophosphate [C6N4H22][ZnPO4](4) 1 has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. It crystallized in the triclinic space group P1 with a = 9.784(2) Angstrom, b = 10.074(2) Angstrom, c = 8.0573(16) Angstrom, alpha = 121.62(3)degrees, beta = 119.20(3)degrees, gamma = 98.37(3)degrees, V = 496.96(17) Angstrom(3), Z = 1. Refinement gave R-1 = 0.0651, wR(2) = 0.1476 for observed data. The zinc and phosphorous atoms are tetrahedrally coordinated by oxygen atoms with a Zn to P ratio of 1. The structure of 1 is constructed by strictly alternating linking of ZnO4 and PO4 with four-membered rings as the secondary building units. The four-membered rings are further connected in three styles: sharing zinc atoms to form a chain structure, connected using vertices to form an undulating chain, and a 4-1 connection. These connections give a complex three-dimensional eight-membered ring channel system. (C) 2002 Elsevier Science (USA).
收录类别	SCI
语种	英语
公开日期	2013-09-24
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/54403]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Zhao, YN,Ju, J,Chen, XM,et al. Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2002,165(1):182.
APA	Zhao, YN,Ju, J,Chen, XM,Li, XH,Wang, RJ,&Mai, ZH.(2002).Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4).JOURNAL OF SOLID STATE CHEMISTRY,165(1),182.
MLA	Zhao, YN,et al."Synthesis and structure of an open-framework zincophosphate [C6N4H22][ZnPO4](4)".JOURNAL OF SOLID STATE CHEMISTRY 165.1(2002):182.