Preparation of Quasi-Free-Standing Graphene with a Super Large Interlayer Distance by Methane Intercalation | |
Huang, Q ; Chen, XL ; Lin, JJ ; Li, K ; Jia, YP ; Liu, J ; Guo, LW ; Wang, WJ ; Wang, G | |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
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2011 | |
卷号 | 115期号:42页码:20538 |
关键词 | EPITAXIAL GRAPHENE RAMAN-SPECTROSCOPY CARBON NANOTUBES ELECTRONIC-PROPERTIES BILAYER GRAPHENE LAYER GRAPHENE SINGLE-LAYER WAFER-SCALE HYDROGEN NANORIBBONS |
ISSN号 | 1932-7447 |
通讯作者 | Chen, XL (reprint author), Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, POB 603, Beijing 100190, Peoples R China. |
中文摘要 | Preparation of high quality graphene with uniform layers currently remains a bottleneck. In particular, graphene with only one large-sized monolayer is very difficult to obtain. With epitaxial growth of graphene under a hydrogen atmosphere and high temperature, even as high as 1550 degrees C, the obtained graphene was intercalated by methane and methyl group (-CH(3)) species. Spontaneously, this intercalation makes the coupling of adjacent layers weak and leads to each layer behaving like free-standing graphene. X-ray diffraction spectra demonstrate that the interdistance of adjacent layers is abnormally large, disclosing each layer suspended by the intercalation, regardless of the layer number. Our findings have opened a possible route to prepare free-standing, high quality graphene effectively in large-scale, behaving like one monolayer free-standing graphene. The Raman spectra also support this conclusion. |
收录类别 | SCI |
资助信息 | Knowledge Innovation Engineering of Chinese Academy of Sciences [KJCX2-YW-W22, YYYJ-0701]; Ministry of Science & Technology of People's Republic of China [2007BAE34B00, 2006AA03A146, 2007CB936300, 2006AA03A107]; National Natural Science Foundation of China [50972162, 50702073, 51072223]; Major State Basic Research Development Program of China (973 Program) [2011CB932700] |
语种 | 英语 |
公开日期 | 2013-09-24 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/51348] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Huang, Q,Chen, XL,Lin, JJ,et al. Preparation of Quasi-Free-Standing Graphene with a Super Large Interlayer Distance by Methane Intercalation[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2011,115(42):20538. |
APA | Huang, Q.,Chen, XL.,Lin, JJ.,Li, K.,Jia, YP.,...&Wang, G.(2011).Preparation of Quasi-Free-Standing Graphene with a Super Large Interlayer Distance by Methane Intercalation.JOURNAL OF PHYSICAL CHEMISTRY C,115(42),20538. |
MLA | Huang, Q,et al."Preparation of Quasi-Free-Standing Graphene with a Super Large Interlayer Distance by Methane Intercalation".JOURNAL OF PHYSICAL CHEMISTRY C 115.42(2011):20538. |
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