Understanding of effects of nano-Al2O3 particles on ionic conductivity of composite polymer electrolytes

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	Understanding of effects of nano-Al2O3 particles on ionic conductivity of composite polymer electrolytes
	Wang, ZX ; Huang, XJ ; Chen, LQ
刊名	ELECTROCHEMICAL AND SOLID STATE LETTERS
	2003
卷号	6 期号:11 页码:E40
关键词	POLYACRYLONITRILE-BASED ELECTROLYTE TRANSPORT-PROPERTIES POLY(ETHYLENE OXIDE) LITHIUM PERCHLORATE SOLID ELECTROLYTES MECHANISM LICLO4 POLYETHYLENE SPECTROSCOPY CARBONATE
ISSN号	1099-0062
通讯作者	Wang, ZX (reprint author), Chinese Acad Sci, Inst Phys, Lab Solid State Ion, POB 603, Beijing 100080, Peoples R China.
中文摘要	Nanosized alumina (Al2O3) was added to polyacrylonitrile (PAN)-lithium perchlorate (LiClO4) electrolytes. Infrared (IR) absorption spectroscopy was employed to study the influence of Al2O3 on the ionic association in the composite electrolyte. The nano-Al2O3 filler helped the dissolution of the salt and the dissociation of nitrile-Li+ interaction in the "dry" composite. Based on the Lewis acid-base type interactions of the surface groups on nano-Al2O3 particles with the ions and with the polymer and on the present and previous experimental results, an interpretation is proposed to the roles of the nanoscale ceramic particles on the enhancement of ionic conductivity and transference number of composite polymer electrolytes. (C) 2003 The Electrochemical Society.
收录类别	SCI
语种	英语
公开日期	2013-09-23
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/46398]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Wang, ZX,Huang, XJ,Chen, LQ. Understanding of effects of nano-Al2O3 particles on ionic conductivity of composite polymer electrolytes[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS,2003,6(11):E40.
APA	Wang, ZX,Huang, XJ,&Chen, LQ.(2003).Understanding of effects of nano-Al2O3 particles on ionic conductivity of composite polymer electrolytes.ELECTROCHEMICAL AND SOLID STATE LETTERS,6(11),E40.
MLA	Wang, ZX,et al."Understanding of effects of nano-Al2O3 particles on ionic conductivity of composite polymer electrolytes".ELECTROCHEMICAL AND SOLID STATE LETTERS 6.11(2003):E40.