Template synthesis and structure of a three-dimensional bimetallic phosphate

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	Template synthesis and structure of a three-dimensional bimetallic phosphate
	Zhao, YN ; Ju, J ; Chen, XM ; Li, XH ; Wang, Y ; Wang, RJ ; Li, M ; Mai, ZH
刊名	JOURNAL OF SOLID STATE CHEMISTRY
	2002
卷号	166 期号:2 页码:369
关键词	ZINC PHOSPHATE GALLIUM PHOSPHATE SOLVOTHERMAL SYNTHESIS HYDROTHERMAL SYNTHESIS COBALT PHOSPHATES METAL PHOSPHATES FRAMEWORK ZINCOPHOSPHATE TETRAHEDRA ROUTE
ISSN号	0022-4596
通讯作者	Zhao, YN (reprint author), Chinese Acad Sci, Inst Phys, POB 603, Beijing 100080, Peoples R China.
中文摘要	Introducing cobalt into the Zn-P-O-amine system and using oxalates as starting materials, an amine-containing open-framework zinc cobalt phosphate, [C2N2H10][Co4.2Zn1.8 (PO4)(4)(HPO4)] (.) H2O (1), has been hydrothermally synthesized. It crystallizes in monoclinic space group C2/c (No. 15) with cell parameters a = 19.214(8) Angstrom, b = 5.0152(17) Angstrom, c = 21.175(8) Angstrom, beta = 103.06(3)degrees, V = 1987.7(13) Angstrom(3), Z = 4, D-cal = 3.078 g cm(-3). The structure contains two sets of M-O-M linkage: M-O-M dimer and unusual infinite helical -M-O-M- chain. Connecting the dimers by phosphates leads to three-membered ring chains. The linking of the helical chains by PO4 groups results in a sheet structure. Using the three-membered ring chains as pillars, stacking of the sheets gives rise to a three-dimensional tunnel structure. (C) 2002 Elsevier Science (USA).
收录类别	SCI
语种	英语
公开日期	2013-09-23
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/44827]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Zhao, YN,Ju, J,Chen, XM,et al. Template synthesis and structure of a three-dimensional bimetallic phosphate[J]. JOURNAL OF SOLID STATE CHEMISTRY,2002,166(2):369.
APA	Zhao, YN.,Ju, J.,Chen, XM.,Li, XH.,Wang, Y.,...&Mai, ZH.(2002).Template synthesis and structure of a three-dimensional bimetallic phosphate.JOURNAL OF SOLID STATE CHEMISTRY,166(2),369.
MLA	Zhao, YN,et al."Template synthesis and structure of a three-dimensional bimetallic phosphate".JOURNAL OF SOLID STATE CHEMISTRY 166.2(2002):369.