LI+ INSERTION INTO MN SPINEL PHASES | |
PISTOIA, G ; WANG, G ; WANG, C | |
刊名 | SOLID STATE IONICS
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1992 | |
卷号 | 58期号:3-4页码:285 |
关键词 | LITHIATED MANGANESE OXIDES LITHIUM NONAQUEOUS CELL ELECTROCHEMICAL CHARACTERIZATION DIOXIDE ELECTRODES EXTRACTION BATTERIES CATHODES |
ISSN号 | 0167-2738 |
通讯作者 | PISTOIA, G: CTR STUDIO ELETTROCHIM & CHIM FIS INTERFASI,CNR,VIA CASTRO LAURENZIANO 7,ROME,ITALY. |
中文摘要 | Partly substituted and unsubstituted Mn spinels have been synthesized at temperatures of 350-450-degrees-C. The inclusion of Cr ions in the cubic spinel structure is particularly effective in catalyzing its formation at low temperature. A spinel of composition LiMn2-xCrxO4.35 (x approximately 0.2-0.4), prepared at 350-370-degrees-C, has a defective structure of low-crystallinity and a high surface area. It can be cycled at 1 mA/cm2 (approximately C/3) with a stabilized capacity of 0.13 Ah/g. Analogous spinels prepared at 450-degrees-C, with or without Cr, have inferior performances. The Li+ diffusion coefficient in the Cr-containing spinel is higher than that of the unsubstituted material. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-18 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/40802] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | PISTOIA, G,WANG, G,WANG, C. LI+ INSERTION INTO MN SPINEL PHASES[J]. SOLID STATE IONICS,1992,58(3-4):285. |
APA | PISTOIA, G,WANG, G,&WANG, C.(1992).LI+ INSERTION INTO MN SPINEL PHASES.SOLID STATE IONICS,58(3-4),285. |
MLA | PISTOIA, G,et al."LI+ INSERTION INTO MN SPINEL PHASES".SOLID STATE IONICS 58.3-4(1992):285. |
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