Identifying Multiple Configurations of Complex Molecules on Metal Surfaces | |
Liu, Q ; Du, SX ; Zhang, YY ; Jiang, N ; Shi, DX ; Gao, HJ | |
刊名 | SMALL
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2012 | |
卷号 | 8期号:6页码:796 |
关键词 | SCANNING TUNNELING MICROSCOPE ATOMIC-FORCE MICROSCOPY MINIMUM ENERGY PATHS ELASTIC BAND METHOD SINGLE-MOLECULE ROTATIONAL MOTION SADDLE-POINTS DIFFUSION SCALE SPECTROSCOPY |
ISSN号 | 1613-6810 |
通讯作者 | Du, SX: Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China. |
中文摘要 | Experimental identification of molecular configurations in diffusion processes of large complex molecules has been a demanding topic in the field of molecular construction at solid surfaces. Such identification is needed in order to control the self-assembly process and the properties and configurations of the resulting structures. This paper provides an overview of state-of-the-art techniques for identification of molecular configurations in motion. First, a brief introduction to the conventional tools is presented, for example, low-energy electron diffraction and IR/Raman spectroscopy. Second, currently used techniques, scanning probe microscopy, and its application in molecular configuration identification are reviewed. In the last part, a methodology combining time-resolved tunneling spectroscopy and density functional theory calculation is reviewed in detail; this strategy has been successfully applied to two typical molecular systems, (t-Bu)4-ZnPc and FePc (where Pc is phthalocyanine), with molecular rotation and laterial diffusion on the Au(111) surface. |
收录类别 | SCI |
资助信息 | Collaborative Research Centre [TRR61]; National Natural Science Foundation of China [10834011]; National Basic Research Program "973" projects of China [2011CB921702, 2011CB808401]; Shanghai Supercomputing Center |
语种 | 英语 |
公开日期 | 2013-09-17 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/39596] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Liu, Q,Du, SX,Zhang, YY,et al. Identifying Multiple Configurations of Complex Molecules on Metal Surfaces[J]. SMALL,2012,8(6):796. |
APA | Liu, Q,Du, SX,Zhang, YY,Jiang, N,Shi, DX,&Gao, HJ.(2012).Identifying Multiple Configurations of Complex Molecules on Metal Surfaces.SMALL,8(6),796. |
MLA | Liu, Q,et al."Identifying Multiple Configurations of Complex Molecules on Metal Surfaces".SMALL 8.6(2012):796. |
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