Crystallization behavior of the amorphous carbon nanotubes prepared by the CVD method | |
Ci, LJ ; Wei, BQ ; Xu, CL ; Liang, J ; Wu, DH ; Xie, SS ; Zhou, WY ; Li, YB ; Liu, ZQ ; Tang, DS | |
刊名 | JOURNAL OF CRYSTAL GROWTH
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2001 | |
卷号 | 233期号:4页码:823 |
关键词 | FLOATING CATALYST METHOD GRAPHITIZATION NANOFIBERS FIBERS |
ISSN号 | 0022-0248 |
通讯作者 | Ci, LJ: Chinese Acad Sci, Inst Phys, Ctr Condensed Matter Phys, Grp 412, POB 603-32, Beijing 100080, Peoples R China. |
中文摘要 | We report the crystallization behavior of the amorphous carbon nanotubes at high temperature in this paper. Transmission electron microscopy and X-ray diffraction were performed to characterize the structures of the carbon nanotubes. The results reveal that the microstructure of the as-grown carbon nanotubes, prepared by the floating catalyst method, is roughly amorphous. The as-grown carbon nanotubes were annealed at high temperatures, and the crystallization behavior of the amorphous carbon nanotubes was investigated systematically. Because the carbon nanotubes have finite dimensions and tube-like shape, their crystallization behavior is completely different from the bulk amorphous carbons. The results reveal that the graphene layers in the annealed carbon nanotubes will form into a uniform two-dimensional turbostratic stack, a configuration of carbon nanotubes with the lower Gibbs free energy. A thermodynamic model is presented to explain the crystallization behavior of the amorphous carbon nanotube. (C) 2001 Elsevier Science B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2013-09-17 |
内容类型 | 期刊论文 |
源URL | [http://ir.iphy.ac.cn/handle/311004/35443] ![]() |
专题 | 物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文 |
推荐引用方式 GB/T 7714 | Ci, LJ,Wei, BQ,Xu, CL,et al. Crystallization behavior of the amorphous carbon nanotubes prepared by the CVD method[J]. JOURNAL OF CRYSTAL GROWTH,2001,233(4):823. |
APA | Ci, LJ.,Wei, BQ.,Xu, CL.,Liang, J.,Wu, DH.,...&Tang, DS.(2001).Crystallization behavior of the amorphous carbon nanotubes prepared by the CVD method.JOURNAL OF CRYSTAL GROWTH,233(4),823. |
MLA | Ci, LJ,et al."Crystallization behavior of the amorphous carbon nanotubes prepared by the CVD method".JOURNAL OF CRYSTAL GROWTH 233.4(2001):823. |
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