A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)

CORC > 物理研究所 > 物理所公开发表论文 > 期刊论文

	A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)
	Liu, CM ; Zhang, DQ ; Luo, JL ; Wang, NL ; Hu, HM ; Zhu, DB
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2003
期号	19 页码:3618
关键词	CENTER-DOT NETWORKS FRAMEWORK MOLECULES COMPLEXES CAVITIES LIGANDS TOPOLOGY COMPOUND SOLIDS
ISSN号	1434-1948
通讯作者	Liu, CM: Chinese Acad Sci, Organ Solids Lab, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China.
中文摘要	The solvothermal reaction between Cu(ClO4)(2).6H(2)O and 2-pyrazinecarboxylic acid in methanol yields a novel mixedvalence Cu-I/Cu-II coordination polymer, (CuCuII)-Cu-I(2-pyrazine-carboxylate)(2)(H2O)(ClO4) (1), in which a three-dimensional supramolecular array with square channels (9.3 x 9.3 Angstrom) is formed through crisscross arrangement of the one-dimensional (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(+) coordination polymer cation chains in the adjacent layers. Complex 1 exhibits weak ferromagnetic interactions. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
收录类别	SCI
语种	英语
公开日期	2013-09-17
内容类型	期刊论文
源URL	[http://ir.iphy.ac.cn/handle/311004/33138]
专题	物理研究所_物理所公开发表论文_物理所公开发表论文_期刊论文
推荐引用方式 GB/T 7714	Liu, CM,Zhang, DQ,Luo, JL,et al. A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2003(19):3618.
APA	Liu, CM,Zhang, DQ,Luo, JL,Wang, NL,Hu, HM,&Zhu, DB.(2003).A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(19),3618.
MLA	Liu, CM,et al."A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .19(2003):3618.