Fast analysis of nitrobenzene by nitroreductase modified electrode
Liu, C. M.; Liu, C. M.; Liu, C. M.
2011
会议名称International Conference on Chemical Engineering and Advanced Materials
会议日期MAY 28-30, 2011
会议地点Changsha, PEOPLES R CHINA
关键词Nitroreductase Modified electrode Triple potential step chronocoulometry Fast analysis Electrochemistry potential step chronoamperometry diffusion-coefficients reduction binding
页码1463-1469
中文摘要Nitroreductase (NR) was modified on glass carbon electrode and used in nitrobenzene analysis. Both cyclic voltammetry (CV) and triple potential step chronocoulometry (TPSC) with a narrow potential step interval were used. The modification of nitroreductase improved the sensitivity and selectivity of nitrobenzene detection. Both the peak area and peak current were examined for quantitative analysis, showing a linear relation between nitrobenzene concentration and peak area, and a logarithmic relation for peak current, with correlation coefficients of 0.9981 and 0.9993, respectively. Statistical tests to evaluate the reliability of TPSC showed that there was no evidence of systematic error, and it was not significantly different from CV or high performance liquid chromatography (HPLC). The new method could avoid most interferents, showing good selectivity.
收录类别CPCI
会议网址://WOS:000304284000311
会议录Advanced Materials Research
会议录出版者Trans Tech Publications Ltd
语种英语
内容类型会议论文
源URL[http://ir.ipe.ac.cn/handle/122111/6531]  
专题过程工程研究所_研究所(批量导入)
推荐引用方式
GB/T 7714
Liu, C. M.,Liu, C. M.,Liu, C. M.. Fast analysis of nitrobenzene by nitroreductase modified electrode[C]. 见:International Conference on Chemical Engineering and Advanced Materials. Changsha, PEOPLES R CHINA. MAY 28-30, 2011.://WOS:000304284000311.
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