Facile Synthesis of Au-Nanoparticle/Polyoxometalate/Graphene Tricomponent Nanohybrids: An Enzyme-Free Electrochemical Biosensor for Hydrogen Peroxide

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 研究所（批量导入）

	Facile Synthesis of Au-Nanoparticle/Polyoxometalate/Graphene Tricomponent Nanohybrids: An Enzyme-Free Electrochemical Biosensor for Hydrogen Peroxide
	Liu, Rongji 1,2; Li, Shiwen 3; Yu, Xuelian 1; Zhang, Guangjin 1; Zhang, Suojiang 1; Yao, Jiannian 4; Keita, Bineta 3; Nadjo, Louis 3; Zhi, Linjie 5
刊名	SMALL
	2012-05-07
卷号	8 期号:9 页码:1398-1406
关键词	Au nanoparticles polyoxometalates graphene hybrids biosensors
ISSN号	1613-6810
其他题名	Small
中文摘要	A green, facile, one-pot synthesis of well-defined Au NPs@POMGNSs tricomponent nanohybrids is reported (POM stands for polyoxometalate and GNSs for graphene nanosheets). The synthesis is convenient, rapid and environmentally friendly. The POMs serve as both reducing, encapsulating molecules, and bridging molecules; this avoids the introduction of other organic toxic molecules. Characterization using transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy analysis is performed, and the structure of the prepared nanohybrids of Au NPs@POMGNSs is verified. Most importantly, the amperometric measurements show the Au NPs@POMGNSs nanohybrids have high catalytic activity with good sensitivity, good long-term stability, wide linear range, low detection limit, and fast response towards H2O2 detection for application as an enzyme-free biosensor. Transformation of the POMs during H2O2 detection does not affect the catalytic activities of the nanohybrids. Thus, the synergistic effect of Au NPs and GNSs in the nanohybrids leads to the enhanced catalytic property.
英文摘要	A green, facile, one-pot synthesis of well-defined Au NPs@POMGNSs tricomponent nanohybrids is reported (POM stands for polyoxometalate and GNSs for graphene nanosheets). The synthesis is convenient, rapid and environmentally friendly. The POMs serve as both reducing, encapsulating molecules, and bridging molecules; this avoids the introduction of other organic toxic molecules. Characterization using transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy analysis is performed, and the structure of the prepared nanohybrids of Au NPs@POMGNSs is verified. Most importantly, the amperometric measurements show the Au NPs@POMGNSs nanohybrids have high catalytic activity with good sensitivity, good long-term stability, wide linear range, low detection limit, and fast response towards H2O2 detection for application as an enzyme-free biosensor. Transformation of the POMs during H2O2 detection does not affect the catalytic activities of the nanohybrids. Thus, the synergistic effect of Au NPs and GNSs in the nanohybrids leads to the enhanced catalytic property.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
研究领域[WOS]	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]	FUNCTIONALIZED GRAPHENE SHEETS ; ELECTROCATALYTIC ACTIVITY ; GLUCOSE BIOSENSOR ; REDUCTION ; FILMS ; OXIDE ; HYBRID ; PHASE ; PHOTOREDUCTION ; NANOPARTICLES
收录类别	SCI
原文出处	://WOS:000303445400016
语种	英语
WOS记录号	WOS:000303445400016
公开日期	2013-11-28
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/6343]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Univ Paris 11, Chim Phys Lab, Equipe Electrochim & Photoelectrochim, UMR CNRS 8000, F-91405 Orsay, France 4.Chinese Acad Sci, Key Lab Photochem, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 5.Natl Ctr Nanosci & Technol China, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Liu, Rongji,Li, Shiwen,Yu, Xuelian,et al. Facile Synthesis of Au-Nanoparticle/Polyoxometalate/Graphene Tricomponent Nanohybrids: An Enzyme-Free Electrochemical Biosensor for Hydrogen Peroxide[J]. SMALL,2012,8(9):1398-1406.
APA	Liu, Rongji.,Li, Shiwen.,Yu, Xuelian.,Zhang, Guangjin.,Zhang, Suojiang.,...&Zhi, Linjie.(2012).Facile Synthesis of Au-Nanoparticle/Polyoxometalate/Graphene Tricomponent Nanohybrids: An Enzyme-Free Electrochemical Biosensor for Hydrogen Peroxide.SMALL,8(9),1398-1406.
MLA	Liu, Rongji,et al."Facile Synthesis of Au-Nanoparticle/Polyoxometalate/Graphene Tricomponent Nanohybrids: An Enzyme-Free Electrochemical Biosensor for Hydrogen Peroxide".SMALL 8.9(2012):1398-1406.